This problem illustrates the application of Linear Variational Theory. Consider a particle of massm in-a-box of length 1 but with a potential energy inside of the box which slopes upwards.V(x) = b(x – ) if 0 < x < 1V(x) = cootherwiseb is a constant which we will take in units of the particle in a box energies:11h?n?b =2mWe will use a set of two basis functions consisting of the n=1 and n=2 particle in a boxeigenfunctions.a. Show that the elements of the Hamiltonian matrix H11 and H22 can be calculated from theusual particle in a box energies.

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This problem illustrates the application of Linear Variational Theory. Consider a particle of mass m in-a-box of length 1 but with a potential energy inside of the box which slopes upwards. V(x) = b(x -) if 0

This problem illustrates the application of Linear Variational Theory. Consider a particle of mass m in-a-box of length 1 but with a potential energy inside of the box which slopes upwards. V(x) = b(x -) if 0

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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