Potassium, a silvery metal, reacts with bromine, a corrosive, reddish liquid, to yield potassium bromide, a white solid. Write the balanced equation, and identify the oxidizing and reducing agents.
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Potassium, a silvery metal, reacts with bromine, a corrosive, reddish liquid, to yield potassium bromide, a white solid. Write the balanced equation, and identify the oxidizing and reducing agents.
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- The density of trifluoroacetic acid vapor was determined at 118.1 °C and 468.5 torr, and found to be 2.784 g/L. Calculate K, for the association of the acid. 0-H...O 2CF,CO,H(g) = CF;C CF,C(g) O----H-OPotassium superoxide, KO2, is used in rebreathing masks to generate oxygen according to the reaction below. If the mask contains 0.250 mol KO2 and 0.200 mol water, what is the limiting reagent? How many moles of excess reactant will there be once the reaction is complete? 4 KO2(s) + 2 H2O(ℓ) → 4 KOH(s) + 3 O2(g)A 1.000-g sample containing bromide was dissolved in sufficient water to give 100.0 mL. A 50.00 mL aliquot was measured and after acidification, silver nitrate was introduced to precipitate AgBr, which was filtered, washed, and then dissolved in an ammoniacal solution of potassium tetracyanonickelate(II): Ni(CN)42- + 2AgBr(s) → 2Ag(CN)2- + Ni2+ + 2Br- The liberated nickel ion required 11.70 mL of 0.002146 M EDTA. The other 50.00 mL remaining solution was also analyzed for its Br- content by potentiometry using a metallic electrode of the second kind. e) Write the cell notation of the potentiometric set-up with SCE as the reference electrode. f) Write the Nernst equation that describes the indicator electrode set-up.
- Determine the fluoride ion concentration for a saturated solution of magnesium fluoride. K sp = 7.4 x 10-11Trans-oleic acid (18:1,D9) has a melting temperature of (44.5C) and cis-oleic acid (18:1,D9) has a melting point of (13.4C). Briefly explain the difference in melting points between the two. tw.The following data was collected for n-pentane and isopentane: Compound P, (kPa) n-pentane 282.9 at 70°C 895.5 at 120°C Isopentane 955.9 at 115°C 1152.4 at 125°C а) Develop a correlation for the vapor pressure of Isopentane as a function of temperature. Clearly state the units. b) Calculate the vapor pressure of Isopentane at 120°C. c) Estimate the heat of vaporization of Isopentane by using the data in the table. A closed container contains a mixture of 65.0 mol% n-pentane and 35.0 mol% isopentane. The system is initially all liquid at 120.0°C and high pressure and the pressure is gradually reduced at a constant temperature. d) i. Calculate the pressure (in kPa) at which the first bubble of vapor forms. ii. What is the composition (in mole fractions) of the first bubble of vapor at the conditions found in part (i)? A new mixture contains cyclohexane (Pv=288.3kPa at 120°C), n-pentane and isopentane at 120°C and high pressure. The pressure is reduced at constant temperature to a point…