Place 2.4 grams of sulfanilic monohydrate in a 125 ml Erlenmayer flask and dissolve it in 25 ml of 25% aqueous sodium carbonate by boiling. Cool the solution in the flask with running water before adding 0.95 gram of sodium nirite with stirring to dissolve the solid. Pour the solution into a 50 ml Erlenmayer flask containing 12.5 grams of ice and 2.5 ml of concentrated hydrochloric acid. Within a few minutes the white diazonium sulfonate inner salt should form a suspension. Transfer half of it to a 100 ml beaker, and keep both containers cold until each is used in later steps.
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- 1. What is the molecular mass of an organic compound if 15.00 g of the compound is dissolved in 225.0 g of carbon tetrachloride raises the boiling point to 85.36 °C? (ebullioscopic constant or kb = 5.03 °C/m) 2. A solution of 12.0 g of a nonvolatile, nondissociating compound dissolved in 0.200 kg of benzene boils at 81.2 °C. Calculate the molecular weight of the compound. (boiling point or Tb of pure benzene: 80.1 °C, ebullioscopic constant for benzene: 2.53 °C/m) 3. A solution contains 23.6 g of a nonelectrolyte and 175 g of water. The water freezes at -7.18° C and Kf = 1.86° C/m. Is the nonelectrolyte CH3OH or C2H5OH?arrow_forward1-A sample of pure t-butyl alcohol weighing 6.22 g was found to have a freezing point of 24.7 °C. When 0.543 g of an unknown compound X was added to the t-butyl alcohol, the mixture had a freezing point of 21.3 °C. Calculate the molar mass of compound X. (Kf = 12.8 °C/molal for t-butyl alcohol.)A sample of pure t-butyl alcohol weighing 6.22 g was found to have a freezing point of 24.7 °C. When 0.543 g of an unknown compound X was added to the t-butyl alcohol, the mixture had a freezing point of 21.3 °C. Calculate the molar mass of compound X. (Kf = 12.8 °C/molal for t-butyl alcohol.) 2-What is the rate law expression for the reaction A + B → C, based on the following dataarrow_forwardCyclonite, also known as RDX (Research Department Explosive), is used to make Semtex, a plastic explosive, when mixed with PETN. Semtex was used in the bomb that brought down PanAm flight 103 over Lockerbie, Scotland in 1988 killing 270 people. RDX is typically recrystallized from acetone. 1 gram of RDX is soluble in 100 mL of cold acetone (0 0C) and in 25.0 mL of boiling acetone. A student performed recrystallization starting with using 5.0 mL of acetone. a. What is the maximum amount of crude RDX the student can purify given this volume of acetone in order to maximize the % recovery? b. A student reported 65% recovery from the process of recrystallization after using 5.0 mL of acetone and the mass that can be used with that volume (part a). Is 65% the maximum % recovery of RDX using the volume you calculated in part a? Show your work.arrow_forward
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- Caffeine can be extracted from tea bags using liquid-liquid extraction. After extracting the tea in hot water, sodium carbonate can be added to form the starting aqueous solution. In a separatory funnel containing 20 mL of diethyl ether, the same volume of aqueous solution will be added. The same procedure will be done in another separatory funnel but this time the organic solvent is hexane. Both separatory funnels will be shaken to release the pressure, and let stand to promote layer separation. The organic layers now containing caffeine will be separated into separate beakers. The beakers were then dried using calcium chloride (CaCl2). The beakers containing both solvents will be dried to obtain the isolated caffeine. Why is it important to release the pressure by venting out the separatory funnel? How will this affect the extraction when bypassed?arrow_forwardAn organic chemistry student isolates 738 mg of salicylic acid (SA) and decides to use methanol in an attempt to purify it by recrystallization. Use the following information to calculate the maximum amount (in mg) that can purified from the crude product. SA solubility in methanol: o°C = 41.3 g/100 mL 56 °C = 64.5 g/100 mLarrow_forward3. You are asked to calculate the Kf for t-butyl alcohol (MW = 74.122 g/mol). You gather the following information in your experiment. You weigh out 2.124 g t-butyl alcohol and you determine the freezing point of the solvent t-butyl alcohol is 21.6 °C (freezing point pure t-butyl alcohol). You then add water to the test tube with the t-butyl alcohol and measure the freezing point to be 15.3 °C. What key piece of information are you missing to calculate the Kf?arrow_forward
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