Part B CH3CH2 CH3 Br2 CH₂Cl₂ CH3CH2 CH2CH3 Draw the molecules on the canvas by choosing buttons from the Tools (for bonds), Atom appropriate stereochemistry by choosing the dashed or wedged buttons and then clickin HD EXP. CONT WV A ΔΟ H с N S H₂C Br CI CH3 Br C Br - H₂C- Од -CH3 P F
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- reactions. Be sure to show any significant stereochemical details. (a) I. Nall. CS 2. CH,I 3. heat (b) 1. BULI, LICI 2.MeCu(CN)LI (c) CH, Zn-Cu CH,l,, ether (d) CH,CO,H LOET (e) Br Zn, THO.(c) (d) (e) HN NHSO₂Ar OH BuLi [3 equivs.], then CO₂ then CF3CO₂H Ar = 2,4,6-tri-isopropylphenyl t-Bu t-BuLi [2 equivs.], then CO₂ (i) BuLi [2equivs.] then DMF, then H3O+ CO₂H HN `t-Bu CHO Na Draw the structure of the intermediate (I) for the reaction below. Hg(O2CCH3)2 NaBH4 Product CH;OH H3C • Use the wedge/hash bond tools to indicate stereochemistry where it exists. If the reaction produces a racemic mixture, just drawv one stereoisomer.
- H H ČH3 Br р. + CH;C=C: in acetone Reaction Type(s) Mechanism(s) Product(s). Stereochemistry (if applicable) q. p-chloronitrobenzene + sodium ethoxide Reaction Type(s) Mechanism(s) Product(s). Stereochemistry (if applicable)Provide the structure of the organic products(s), which result in the reaction below. (Hint: it's a substitution product; show stereochemistry joll| CI CH3 Br CH3CH₂OH CNDetermine the double bond stereochemistry (E or Z) for the following molecules. F. H3C C A CH3 F. H B D Br
- Meeka X me X OWLv2 | Online teaching X ment/takeCovalentActivity.do?locator-assignment-take&takeAssignmentSessi AGP [Review Topics] [References] Draw a structural formula for the major organic product of the following reaction: CH₂Cl₂ -CH=CHCH3 + Br₂ sited Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. . Do not show stereochemistry in other cases. If enantiomers are formed, just draw one. & SP Ⓒ- 1 30 - IF 11:00 PM/&:&$((($:&:&:&;$Give the major organic product(s) of the following. Include stereochemistry when applicable. 1) Nal Br a) 2) NaCN, acetone 1) NaOC(CH3)3, heat d Br 2) BH₂ THF; 3) H,O,, NaOH(aq) b) c) d) c) 2) KOC(CH3)3, heat Copyright University of California Merced 2022 Br 1) NaOH, heat 2) MCPBA 1) KOC(CH3)3, heat 2) H3O+