NAD+ NADH + H* NAD* NADH + H* ܘ H CH3-CH2-OH - ADH » CH3-C=O - ALDH » CH3-C-OH Ethanol Acetaldehyde Acetate
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Please answer the following answer:
Ethanol
Excess consumption of ethanol leads to the accumulation of NADH. What effect would a high concentration of NADH have on metabolic pathways and consequently the body. Choose as least two pathways to describe the effect.
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- H H H-C-OH CH-Q HOOHH H OH Glucose H-C=O H-C-H H H-C=0 ATP ADP H-C-OH HO-C-H H-C-OH Н Pyruvate OH Hexokinase ATP ADP IVE pyruvate kinase H-C-O-P-0 Glucose 6-phosphate (PEP) GLYCOLYSIS H-C-O-P=O H-C-OHO-H-C-OHO kinase isomerase но Phosphoenolpyruvate H-C-OH ÇO ATP ADP HO-C-H H-C-OH HO-C-H Phosphofructo H-C-OH aldose H-C-OHỌ H-C-O-P-0 HO Fructose 1, 6-bisphosphate H-C-O-P=O H 6- Fructose 6-phosphate H H-C-O-P=O C=O 6- Fructose bisphosphate H-C-OHO ATP 9 H H-C-O-PO C=O o- HO-C-H Dihydroxyacetone phosphate H ADP Glyceraldehyde 3-phosphate dehydrogenase 2X Triose phosphate isomerase H c=0 H-C-OHO H-C-O-PO 3-phosphate Hỏ NAD + P NADH+H* -O-P=O Ó c=0 Glyceraldehyde N H-C-O-P-O Enolase H-OHO phosphoglycerates-C-O-P-0 phosphoglycerate HC-OHO kinase H H-C-O-P=O Ĥ 6- 2-Phosphoglycerate 3-Phosphoglycerate 1,3-BisphosphoglycerateWhich of the compounds shown below exhibit a high negative free energy of hydrolysis equal to or larger than the free energy of hydrolysis for the phosphoanhydride of ATP? (Choose all that apply) В Α HPΗ Ho HO HO H2N-CH-C CH2 H2N-CH-C CH2 CH2 H2N-CH-Ö CH2 C CH2 D E O A O B O E O=p-00 O=p-00 O=-00 O=0-00 O=L-00Match each of the enzymes involved in de novo pyrimidine synthesis with the correct description: _______ Dihydroorotate dehydrogenase _______ UMP synthase_______ Carbamoyl phosphate synthetase II _______ TMP synthase _______ CTP synthetase_______ Aspartate transcarbamoylase _______ PRPP synthetase (A) attaches an aspartate to an activated carbamoyl molecule(B) bifunctional enzyme that combines a nitrogenase pyrimidine ring to an activated ribose(C) catalyzes the formation of the activated ribose sugar(D) uses glutamine to add an amine to a preformed nucleotide(E) produces the first cyclic nitrogenase ring during de novo pyrimidine synthesis(F) combines bicarbonate and nitrogen from glutamine in the first step of pyrimidine ring synthesis (G) uses a folate derivative to add a methyl group to a preformed nucleotide
- The enzyme is considered to be alan * ÇOO ÇOO Lactate dehydrogenase HO-C-H+ NAD C=0 + NADH + H CH: Pyruvate Lactate O Oxydoreductase O Isomerase O Hydrolase O Ligase O DehydrataseQUESTION 3 Bioremediation is a branch of biotechnology that employs the use of living organisms to remove toxic substances; such as, mercury, radioactive material, industrial waste, and the petroleum products of oil spills from the water and soil in our environment. Here is a figure that shows the bacterial degradation of the poly-aromatic hydrocarbon, naphthalene. In this figure showing the catabolic metabolism of naphthalene, would you predict the metabolites catechol, salicylate, and gentisate generated in this process to (select one): Proposed catabolic pathways of naphthalene by bacteria 1,2-Naphthoquinone Coumarin Catechol OH OHL 35-8-8-8-8 OH OH Naphthalene cis-1,2-Dihydroxy- 1,2-dihydronaphthalene 1,2-Dihydroxynaphthalene O COOH OH 2-Hydroxy-2H-chromene- 2-carboxylic acid cis-o-Hydroxybenzalpyruvate COOH 2-Hydroxybenzaldehyde OH Gentisate COOHComplete the balanced equation for the overall reaction. Select answer choice in between brackets. Sucrose + [2 Pi, 4Pi]+[4 ADP, 2 ADP, 4 ATP, 2ATP]+[2 NAD+, 4 NAD+, 6 NAD+]+[H2O, 5 H2O, 3 H2O] --> [2 cirate, 2 oxaloacetate, 2 pyruvate, 2 acetyl-coA]+[4 ADP, 2 ADP, 4 ATP, 2ATP] + [2 NAD+, 4 NAD+, 6 NAD+] + [2H+, 8H+, 6 H+, 4 H+, 10 H+] Does the commercial process require aerated culture medium—that is, is this a fermentation or an aerobic process? A. a fermentation process, because A. niger cells must use O2O2 to continuously regenerate NAD+ B. an aerobic process, because A. niger cells must use O2O2 to continuously regenerate NAD+ C. a fermentation process, because A. niger cells cannot use O2O2 to continuously regenerate NAD+ D. an aerobic process, because A. niger cells cannot use O2O2 to continuously regenerate NAD+
- Arrange the following order of chemical events of how ribulose reacts in the light independent reaction of photosynthesis starting from ribulose. Fructose 6-phosphate + PGAL Ribulose 5-phosphate Ribulose 1-5 biphosphate Fructose 6-phosphoglyceraldehyde + PGAL Glyceraldehyde 3-phosphate 1,3-biphosphoglyceric acid 3-phosphoglyceric acid Fructose 1,6-biphosphate + PGAL RibuloseGlutamate is derived from which of the following molecules? oxaloacetate pyruvate O 3-phosphoglycerate chorismate O a-ketoglutarateHis388 Glu357 His388 Glu357 Ring opening Proton HO HO abstraction HO но- G6P He NH- NH His388 His388 His388 Glu357 Glu357 Glu357 HO но HO но- но OH cis-enediol F6P Ring closure intermediate OH Describe the mechanism shown above for phosphoglucose isomerase. Describe the chemistry of each step • How the enzyme appears or might facilitate the chemistry How the enzyme increases the reaction rate.
- Indicate the general type of enzyme that mediates each glycolysis reaction depicted below. (e.g. Transferase, Oxidoreductase, Kinase, Hydrolase, Lyase, or Isomerase) iii. O H Glyceraldehyde-3-phosphate → 1,3-Bisphosphoglycerate H-C-OH + NAD CH₂O-P + P₁ H-O- -C-H Glucose →→ Glucose-6-phosphate H b 0 OH HO OH H-C- 0 -H HO- H ОН H-C-OH + NADH +H+ CH₂O P P ATP ADP 1 H (P-O- -C- H H HO OH 2-Phosphoglycerate → Phosphoenolpyruvate 0 OH H ОН -O~(P) + HOHHO-C-CH,-CH,~ Identify the enzyme needed in each of the following reactions as an isomerase, a decarboxylase, a dehydrogenase, a protease, or a phosphatase. о CH;-C-Č-OH → CH;-Č–H + CO, СНО CH,OH НС—ОН C=0 HO-CH — НО -СН НС—ОН НС—ОН HO-CH Но -СH CH-OPO,?- ČH-OPO,- Но -С—СН,—CH, —С—ОН — Но -С—СН—СH-С-ОН + 2Н H;N-CH-C-NH-CH-CO0 +H;O → CH; ČH3 2 H;N-CH-CO0- ČH3CH,-C-CoA + H,0 Acetyl-CoA CoA Çoo CH, но-с-соо čoo CH, Citrate coo Oxaloacetate NADH çoo CH-OH CH, CH, сн-соо NAD Malate HO-C-H Coo Isocitrate CoO NAD çoo NADH • H • Co, CH HC Fumarate čoo a-ketoglutarate CH, FADH, CH, NAD + COA FAD c=o NADH • H CO0 Succinate Coo • co, CH, GTP + COA CH, Succinyl-CoA GOP • P, Coo COA Given the ultimate purpose of the citric acid cycle it is likely that the following would be negative regulators of this cycle. A. NADH and NAD* В. NAD* and AMP ATP and NADH C. ADP and NAD* D. ADP and NADH Е.