K Problem 13 of 40 Submit Curved arrows are used to illustrate the flow of electrons. Follow the arrows and draw the first intermediate formed in this reaction. Include all lone pairs. Ignore any inorganic byproducts. Br----Br----FeBr3 Q Draw Arenium Intermediate
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- 2) For the following reactions, with arrow pushing shown, please indicate whether the reaction/products/arrow pushing is possible (as drawn with curved arrows). If its not possible, briefly describe what the error is. H2N H4N NH4 + OH H3NWhat is the major organic ppoduct of the following reaction? CN CN CN CN 1 CN 3 HWhat is the structure of the intermediate for this reaction? NO2 CH3O NO2 O₂N- CI O₂N CH3OH ✓ -OCH 3 NO₂ CI OCH3 NO₂ XOCH 3 -CH O₂N- NO2 O₂N- NO2 13
- Which reaction intermediate is formed when the following reaction is run in CCl4 as a solvent? Br + Br₂ Br BrAn elevated level of the enzyme alkaline phosphatase (ALP) in human serum is an indication of possible liver or bone disorder. The level of serum ALP is so low that it is very difficult to measure directly. However. ALP catalyzes a number of reactions, and its relative concentration can be determined by measuring the rate of one of these reactions under controlled conditions. One such reaction is the conversion of p-nitrophenyI phosphate (PNPP) to p-nitrophenoxide ion (PNP) and phosphate ion. Control of temperature during the test is very important; the rate of the reaction increases 1.47 times if the temperature changes from 30 C to 37 C. What is the activation energy for the ALP-catalyzed conversion of PNPP to PNP and phosphate?. Provide a synthetic pathway for each of the following multi-step reactions. Do not write any step wise mechanisms. CN HO Br OH SH „Br
- Which of the following is an elimination reaction? ОН (A) CI (B) Br SH (C) CI (D) O ADraw the structure of the missing reactants, intermediates, or products in the following mechanism. Include all lone pairs except on metal atoms. Ignore stereochemistry. Ignore inorganic byproducts. OAc OAc Edit MercurinÂum Intermediate4. For the following reaction scheme, identify by drawing the reagents a, c and d and the intermediate b that are formed in the synthesis of 2-phenylethanoic acid. a Br b CO2 Br d. HO,
- NH3(g) + HCIO4(1) E→ NH,CI0,(s) A B C D Ep E, Ep - R P R P R R Reaction Path Reaction Path Reaction Path Reaction Path A- Which of the following step in the reaction scheme is either out of order or correct and will not lead the reactant to the final product? 1 2 CI 4 5 Step 1 Cl2 with FeCl3 Step 2 Mg followed by CO2 and then HgO* Step 3 H2CRO4 and H2SO4 as catalyst O Step 4 LIAIH4 in tetrahydrofuran followed by H3O* Step 5. PCI3 in pyridine All steps are correct and/or all steps are in the correct orderWrite the reaction flow chart fir the following condensation and further heating of resulting products