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- 6) Provide the enantiomeric Diels-Alder adducts that would form from the following reaction along with the two transition states leading to them: + HO₂CWhat are the products of the below diels-alder reactions? Include stereochemistry!!!! 1a) 1b) 1c) Br =CN & Br1) Which diene can undergo Diels-Alder reaction? gj d)
- 3. Predict the products of the following Diels-Alder reactions. a. b. NC CN3) How could you use Diels-Alder reactions to prepare the following products? Show the starting diene and dienophile in each case H a. b. C. H H d. H .CO₂CH3 CNWhich of the following is the most reactive diene in a Diels-Alder reaction? A) I B) II CI D) IV IV
- The following triene undergoes an intramolecular Diels-Alder reaction to give a bicyclic product. Propose a structural formula for the product. Account for the observation that the Diels-Alder reaction given in this problem takes place under milder conditions (at lower temperature) than the analogous Diels-Alder reaction shown in Problem 20.34.9. Determine the product of the following Diels-Alder reaction. CO₂Et 206°C4) Identify the reagents to prepare the following compound via Diels-Alder reaction Coalf DI Caotl a) X + .wolt •Looft b) x + you to c) of + Xco coot الاك d) None
- 4 predict the diels alder starting material3. The following reactions are not technically the Diels-Alder reaction, but you should still be able to predict the product (with appropriate regio/stereochemistry). (a) (b) OMe OMe H3C N + NC H3C. CN CH32) Rank the following dienes in order of increasing rate of Diels-Alder reaction with maleic anhydride. You do not need to explain your ranking. H3C. H3CO Diene A Diene B Diene C