Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Write the equation for this reaction.
Write the general form of the rate law for this reaction.
which factor, if any, in the rate law changes if temperature is changed?
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- An elementary step is defined as a chemical collision in a reaction mechanism. A collection of different types of collisions makes up the reaction mechanism, so elementary steps provide a molecular view of the overall reaction. Write the rate law for the following reaction, which represents an elementary step in a reaction. Your rate law should not include the states of matter. $$SO2Cl2(g)SO2(g)+Cl2(g)arrow_forwardSome measurements of the initial rate of a certain reaction are given in the table below. Use this information to write a rate law for this reaction, and calculate the value of the rate constant k. Round your value for the rate constant to 3 significant digits. Also be sure your answer has the correct unit symbol.arrow_forwardSuppose the decomposition of ozone proceeds by the following mechanism: step elementary reaction rate constant 1 03(g) O₂(g) + 0(g) k₁ 2 03(g) + O(g) → 20₂(g) k₂ Suppose also k₁ »k₂. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally- observable rate law for the overall chemical reaction. rate = k Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of K₁, K2, and (if necessary) the rate constants k.1 and k-2 for the reverse of the two elementary reactions in the mechanism. = 0 k = 00 X 5 S ?arrow_forward
- Some measurements of the initial rate of a certain reaction are given in the table below. [N] 0.815M1.56M N,|H||initial rate of reaction 185. M/s 141.M/s Use this information to write a rate law for this reaction, and calculate the value of the rate constant k. Round your value for the rate constant to 3 significant digits. Also be sure your answer has the correct unit symbol. 口 rate = 0 ロ || = 1 Explanation Check D2022 McGrny Hl LLC. Al Rights Reserved. Terms of N 回 至 五arrow_forwardO KINETICS AND EQUILIBRIUM Deducing a rate law from initial reaction rate data Some measurements of the initial rate of a certain reaction are given in the table below. H, I, initial rate of reaction 0.735 M 0.260 M 78.0M/s 0.735 M 0.341 M 102. M/s 0.354 M 0.260 M 37.6M/s Use this information to write a rate law for this reaction, and calculate the value of the rate constant k. Round your value for the rate constant to 3 significant digits. Also be sure your answer has the correct unit symbol. Do rate = k| x10 k = Explanation Check © 2021 McGraw-Hill Educat IIarrow_forwardWhich of the following is not an example of heterogeneous catalysis? a) 2O3(g) → 3O2(g) has a catalyst of Cl(g) b) CO(g) + 3H2(g) → CH4(g)+H2O(g) has a catalyst of Co(s) c) C2H4(g) + H2(g) → C2H6(g) has a catalyst of Ni(s) d) 2CO(g) + 2NO(g) → 2CO2(g)+N2(g) has a catalyst Rh(s)arrow_forward
- = Using a rate law The rate of a certain reaction is given by the following rate law: rate = k[H₂ ] [NH₂] Use this information to answer the questions below. What is the reaction order in H₂? What is the reaction order in NH3? What is overall reaction order? At a certain concentration of H₂ and NH3, the initial rate of reaction is 17.0 M/s. What would the initial rate of the reaction be if the concentration of H₂ were doubled? Be sure your answer has the correct number of significant digits. The rate of the reaction is measured to be 2.0 x 10³ M/s when [H₂] = 0.75 M and [NH₂] = 0.44 M. Calculate the value of the rate constant. Be sure your answer has the correct number of significant digits. k= 0 0 04/ -1 X 1/5arrow_forwardThe rate of a certain reaction is given by the following rate law: rate = k[N,][H] Use this information to answer the questions below.arrow_forwardDeducing a rate law from initial reaction rate data Some measurements of the initial rate of a certain reaction are given in the table below. [N] [H] initial rate of reaction 0.977 M 1.26 M 0.162 M/s 2.87 M 1.26 M 1.40 M/s 0.977 M 2.13 M 0.274 M/s Use this information to write a rate law for this reaction, and calculate the value of the rate constant k. Round your value for the rate constant to 3 significant digits. Also be sure your answer has the correct unit symbol. rate = kO k = 0 Explanation Check O 2021 McGraw-Hill Education, All Rights Type here to search 立arrow_forward
- True or False _____ The kinetics of reaction deals with the energies of the products and the reactants. _____ Thermodynamics deals with reaction rates. _____ Understanding the reactions kinetics can help you understand the mechanism of a reaction. _____ Transition states are stable. _____ This is an example of an overall second order reaction (rate = kr[CH3Br][CH3-]) _____ The rate determining step is the step with the lowest activation energy.arrow_forwardDeducing a rate law from initial reaction rate data Some measurements of the initial rate of a certain reaction are given in the table below. N2 Hinitial rate of reaction 2.21 M 2.33 M 35.0 M/s 2.21 M 4.98 M 160. M/s 7.27 M 2.33 M 379. M/s Use this information to write a rate law for this reaction, and calculate the value of the rate constant k. Round your value for the rate constant to 3 significant digits. Also be sure your answer has the correct unit symbol. rate = k M k = Explanation Check 2021 McGraw Hill Educabon. All R P Type here to search 近arrow_forward
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