Identify the two characteristic arrow-pushing patterns that are required for this mechanism: O proton transfer O loss of a leaving group O carbocation rearrangement O nucleophilic attack

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.67QE
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The following rate equation has been experimentally established for this process:
Rate = = K[HOT][CH3CH₂Br]
The energy diagram for this process is shown below:
Free
energy
(G)
50
H₂C
H-C-Br
H
Reaction coordinate
CH3
HO-C-H+
H
Identify the two characteristic arrow-pushing patterns that are required for this mechanism:
O
Br
Transcribed Image Text:The following rate equation has been experimentally established for this process: Rate = = K[HOT][CH3CH₂Br] The energy diagram for this process is shown below: Free energy (G) 50 H₂C H-C-Br H Reaction coordinate CH3 HO-C-H+ H Identify the two characteristic arrow-pushing patterns that are required for this mechanism: O Br
2
W
S
X
O proton transfer
O loss of a leaving group
O carbocation rearrangement
O nucleophilic attack
3
с
188
4
e
D
d
Identify the two characteristic arrow-pushing patterns that are required for this mechanism:
C
f
HO
V
%
5
t
H—C—Br
H
6.0
OMEDEL
6
Oll
b
Reaction coordinate
y
hip
h
&
7
u
CH3
O
HO-C-H + Br
H
n
*
8
j
i
m
9
k
0
Transcribed Image Text:2 W S X O proton transfer O loss of a leaving group O carbocation rearrangement O nucleophilic attack 3 с 188 4 e D d Identify the two characteristic arrow-pushing patterns that are required for this mechanism: C f HO V % 5 t H—C—Br H 6.0 OMEDEL 6 Oll b Reaction coordinate y hip h & 7 u CH3 O HO-C-H + Br H n * 8 j i m 9 k 0
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