Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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How does the spontaneity of the process relate to the Ksp?
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- At what points in the Chapman cycle do photochemical reactions take place?arrow_forwardOne of the important reactions in the biochemical pathway glycolysis is the reaction of glucose-6-phosphate (G6P) to form fructose-6-phosphate (F6P): G6PF6PG298=1.7kJ (a) Is the reaction spontaneous or nonspontaneous under standard thermodynamic conditions?. (b) Standard thermodynamic conditions imply the concentrations of G6P and F6P to be 1 M, however, in a typical cell, they are not even Close to these values. Calculate G when the concentrations of G6P and F6P are 120 M and 28 M respectively, and discuss the spontaneity of the forward reaction under these conditions. Assume the temperature is 37 C.arrow_forwardWhen glucose, C6H12O11, is metabolized to CO2 and H2O in living systems, the first step is the conversion of glucose to glucose-6-phosphate. glucose+H3PO4glucose-6-phosphate+H2OG=13.4kJ This nonspontaneous reaction can be made to proceed by coupling it with the hydrolysis of ATP. ATP+H2OADP+H3PO4G=31.0kJ (a) Write an equation for the coupled reaction and calculate G°. (b) Estimate the number of moles of ATP required to convert glucose to glucose-6-phosphate.arrow_forward
- What is the difference between G, G, and G 298 for a chemical Change?arrow_forwardIs the formation of ozone (O3(g)) from oxygen (O2(g)) spontaneous at room temperature under standard state conditions?arrow_forwardConsider planet Earth as a thermodynamic system. Is Earth thermodynamically or kinetically stable? Discuss your choice, providing as many arguments as you can tosupport it.arrow_forward
- Consider the following reactions at 25°C: C6H12O6(aq)+6O2(g)6CO2(g)+6H2O G=2870kJ ADP(aq)+HPO42(aq)+2H+(aq)ATP(aq)+H2OG=31kJ Write an equation for a coupled reaction between glucose, C6H12O6, and ADP in which G=390kJ .arrow_forwardHow does the spontaneity of the process relate to the Ksp?arrow_forwardIn glycolysis, the hydrolysis of ATP to ADP is used to drive the phosphorylation of glucose (GLC): GLC+ATP <--> ADP+GLC-6-phosphat ΔG° = −17.7 kJ What is the value of Kc for this reaction at 298K?arrow_forward
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