Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- A chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 15.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = -1207. kJ J AS = -4236. K P,(g) + 6CL, (3) 4PCI, (g) AG = kJ Which is spontaneous? O this reaction O the reverse reaction O neither AH = -76. kJ AS = 2NO(g) + CL, (3) → 2NOC1(g)…arrow_forwardFor each chemical reaction listed in the first column of the table below, predict the sign (positive or negative) of the reaction entropy AS. If it's not possible to decide with the information given, check the "not enough information" button in the last column. rxn Note for advanced students: Assume the temperature remains constant. Assume all gases and solutions are ideal. reaction N₂(g) + 3H₂(g) 2NH₂(g) Ba(OH), 8H₂O(s) + 2NH₂Cl(s) BaCl,(aq) +2NH, (aq) + 10H,O(l) HCl(g) + NH₂(g) NH,C1(s) sign of reaction entropy AS 0 rxn not enough information. AS 0 rxn O not enough information. AS 0 rxn not enough information. S 0arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 130.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. Al₂O3(s) + 2Fe(s) → 2Al(s) + Fe₂O3(s) CO₂(g) + 2H₂O(g) → CH₂(g) + 20₂(g) AH = 852. kJ AS = 2044. AG = | KJ Which is spontaneous? this reaction the reverse reaction neither = 803. kJ…arrow_forward
- Using the thermodynamic information in the ALEKS Data tab, calculate the standard reaction entropy of the following chemical reaction: 2NOC1 (g) → 2NO(g) + Cl₂ (g) Round your answer to zero decimal places. 0 x10 X Śarrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 123.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. alo Ar AH = 1353. kJ J AS = 3371. K 2co, (g) + 4H,0(g) → 2CH,он (g) + зо, (з) AG = ||| kJ Which is spontaneous? this reaction the reverse reaction neitherarrow_forwardHello please help me with this thank you!arrow_forward
- Please round to 2 sigfigs!arrow_forwardFor each chemical reaction listed in the first column of the table below, predict the sign (positive or negative) of the reaction entropy AS, If it's not Ixn" possible to decide with the information given, check the "not enough information" button in the last column. Note for advanced students: Assume the temperature remains constant. Assume all gases and solutions are ideal. reaction sign of reaction entropy AS 0 AS rxn not enough information. AS 0 AS rxn not enough information. AS 0 not enough information. ?arrow_forwardFor each chemical reaction listed in the first column of the table below, predict the sign (positive or negative) of the reaction entropy A.Sxn If it's not possible to decide with the information given, check the "not enough information" button in the last column. Note for advanced students: Assume the temperature remains constant. Assume all gases and solutions are ideal. reaction H₂O(/) + AL₂ S₂ (s) → H₂S (g) + Al₂O₂ (s) 2C₂H, (g) + 70₂(g) → 4CO₂(g) + 6H₂O(g) BaCl₂ (aq) + K₂SO4 (aq) BaSO₂ (s) + 2K Cl(aq) sign of reaction entropy AS rxn AS rxn not enough information. AS 0 X 0 rxn not enough information. 3arrow_forward
- Calculate the entropy change in surroundings when 1.00 mol of H:0 (1) is formed under standard conditions, A:H = -286 kJmol1. Industrially, methanol is synthesized using the reaction Co(e) + 2 H2(g) =CH:OH(g) Calculate the equilibrium constant at 298 K. AGP CO(g) = -137.2 kJ/mol; AGP H: (g)= 0; AGP CH:OH(g) = -162 kJ/molarrow_forwardCalculate the standard reaction entropy (∆????∅) at 298 K for the reaction of carbon dioxide with calcium oxide which proceeds according to the following:CaO(?) + CO2(?) → ?aCO3(?)arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 72.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. C₂H₂(g) + 50₂(g) → 3CO₂(g) + 4H₂O(1) 2CO₂ (g) + 4H₂O(g) → 2CH, OH (g) + 30₂ (g) ΔΗ = -1220. ΚΙ J K AS-6432. AG - KJ Which is spontaneous? O this reaction O the reverse reaction…arrow_forward
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