Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- For each chemical reaction listed in the first column of the table below, predict the sign (positive or negative) of the reaction entropy ASxn: If it's not possible to decide with the information given, check the "not enough information" button in the last column. Note for advanced students: Assume the temperature remains constant. Assume all gases and solutions are ideal. reaction sign of reaction entropy AS rxn く0 H,so,(1) + H,0 (1) → H,0" (aq) + HSo, (aq) AS > 0 rxn not enough information. AS く0 rxn 4Fe(s) + 30, (g) → 2Fe,O,(s) AS > 0 rxn not enough information. AS 0 AS rxn not enough information.arrow_forwardIn each , she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 83.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction andAS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = -1237, kJ AS = -3507. K 6C (s) + 6H, (g) + 30,(g) → C,H,o(6) AG = Which is spontaneous? O this reaction the reverse reaction O neither AH = -1648. kJ AS = AG = 0. kJ 4Fe(s) + 30, (g) → 2Fe,0,(s) Which is spontaneous? this reaction O the reverse reaction O…arrow_forwardFor the reaction 2 PbO (s) + 2 SO2 (g) 2 PbS (s) + 3 O2 (g), it can be calculated from AG°F values that AG°298 = %3D +780.8 kJ. What is AG (in kJ) at 298 K when the pressures of the gases are P(SO2) = 120 atm and P(O2) = 3.1 x 107 atm? O - 916 + 916 + 732 O + 722 O + 646arrow_forward
- A chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 91.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = 439. kJ J AS = 1206. K AG = || kJ 4H,PO,(s) → P,0,10 (s) + 6H,0(1) Which is spontaneous? this reaction the reverse reaction neither AH = -803. kJ J AS = K AG = -4. kJ CH, (3) +…arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 25.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = 1005. kJ AS = 3281. K AG = 4PF, (g) + 10H, (3) - P (s) + 20HF (g) Which is spontaneous? O this reaction the reverse reaction O neither AH = 1648. kJ AS = AG = 0. kJ 2Fe, 0, (5)…arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 51.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 6C(s) + 6H2(g) + 30, (g) C6H12O6 (5) AH=1237. kJ AS = -3816. K 2CO2(g) 4H.O(g) → 2CH, OH (g) + 302(g) AG= kJ Which is spontaneous? this reaction the reverse reaction neither AH =…arrow_forward
- 4PC13 (9) P4(g) + 6C₁₂ (g) → C₂H₂ (g) + 502(g) → 3CO2(g) + 3CO2(g) + 4H2O(1) AH 1207. kJ AS = 3078. J - K AG = kJ Which is spontaneous? this reaction the reverse reaction neither ΔΗ = - 2220. ΚΙ AS = K AG = 20. kJ Which is spontaneous? this reaction the reverse reaction neitherarrow_forwardDo not answer in image format. Maintain accuracy and quality in your answer. Answer completely.arrow_forwardIn each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 106.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. 4H, PO () PO () + 6H₂O(0) 6C(s) + 6H₂(e) + 30,(e) - CH₂0,6) Alf 439 kJ AS 1091 - k AG= J Which is spontaneous? this reaction the reverse reaction neither AH-1237 13 AS= AG=-14. U Which is spontaneous? this reaction the reverse reaction neitherarrow_forward
- At 298 K, this reaction to produce phosphoryl chloride has a standard enthalpy of A,H° = -620.2 kJ mol-¹. 2 PCI (g) + O₂(g) → 2 POCI3(1) The standard molar entropies, in J K-1 mol-1, for these species are: PC13(g) [308.5]; O2(g) [205.1]; POCI3(1) [215]. What is the standard Gibbs energy of reaction at 298 K? (Note: Some of these numbers have been changed from their actual values for the purpose of the exam.) (Determine answer in units of kJ/mol with one decimal place. However, do not enter units with your answer.)arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, she fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 106.0 °C and constant total pressure. Then, she measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of her measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. MgO (s) + 2HC1(g) → MgCl₂ (s) + H₂O (1) P₁(s) + 20HF (g) → - 4PF₂ (g) + 10H₂(g) AH-140. kJ AS 454. AG = OKJ Which is spontaneous? Othis reaction AS = K the reverse reaction O…arrow_forwardA chemical engineer is studying the two reactions shown in the table below. In each case, he fills a reaction vessel with some mixture of the reactants and products at a constant temperature of 20.0 °C and constant total pressure. Then, he measures the reaction enthalpy AH and reaction entropy AS of the first reaction, and the reaction enthalpy AH and reaction free energy AG of the second reaction. The results of his measurements are shown in the table. Complete the table. That is, calculate AG for the first reaction and AS for the second. (Round your answer to zero decimal places.) Then, decide whether, under the conditions the engineer has set up, the reaction is spontaneous, the reverse reaction is spontaneous, or neither forward nor reverse reaction is spontaneous because the system is at equilibrium. AH = - - 1212. kJ J AS 4174. K Ś ? AG = 4H₂O₂ (1) + PbS (s) PbSO4 (s) + 4H₂O (1) ☐ kJ Which is spontaneous? this reaction the reverse reaction neither - 1237. KJ 6C (s) + 6H₂(g) + 30₂…arrow_forward
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