Determine the concentration of H+ in each solution at 25°C. A solution with pH = 1.0. [H*] : M A solution with pH = 4.0. [H*] = M A solution with pOH = 11.0. [H*] M

A solution of sodium cyanide, NaCN, has a pH of 12.10. How many grams of NaCN are in 425 mL of a solution with the same pH?

Students are often surprised to learn that organic acids, such as acetic acid, contain OH groups. Actually, all oxyacids contain hydroxyl groups. Sulfuric acid, usually written as H2SO4, has the structural formula SO2(OH)2, where S is the central atom. Identify the acids whose structural formulas are shown below. Why do they behave as acids, while NaOH and KOH are bases? a. SO(OH)2 b. ClO2(OH) c. HPO(OH)2

Consider the following ions: NH4+, CO32, Br, S2, and ClO4. (a) Which of these ions in water gives an acidic solution and which gives a basic solution? (b) Which of these anions will have no effect on the pH of an aqueous solution? (c) Which ion is the strong base? (d) Write a chemical equation for the reaction of each basic anion with water.

What is a salt? List some anions that behave as weak bases in water. List some anions that have no basic properties in water. List some cations that behave as weak acids in water. List some cations that have no acidic properties in water. Using these lists, give some formulas for salts that have only weak base properties in water. What strategy would you use to solve for the pH of these basic salt solutions? Identify some salts that have only weak acid properties in water. What strategy would you use to solve for the pH of these acidic salt solutions? Identify some salts that have no acidic or basic properties in water (produce neutral solutions). When a salt contains both a weak acid ion and a weak base ion, how do you predict whether the solution pH is acidic, basic, or neutral?

The pH of 1.0 108 M hydrochloric acid is not 8.00. The correct pH can be calculated by considering the relationship between the molarities of the three principal ions in the solution (H+, Cl, and OH). These molarities can be calculated from algebraic equations that can be derived from the considerations given below. a. The solution is electrically neutral. b. The hydrochloric acid can be assumed to be 100% ionized. c. The product of the molarities of the hydronium ions and the hydroxide ions must equal Kw. Calculate the pH of a 1.0 108-M HCl solution.

Draw a curve similar to that shown in Figure 14.23 for a series of solutions of NH3. Plot [OH-] on the vertical axis and the total concentration of NH3 (both ionized and nonionized NH3 molecules) on the horizontal axis. Let the total concentration of NH3 vary from 11010M to 1102M.

Using the diagrams shown in Problem 10-117, which of the solutions would have the greatest buffer capacity, that is, greatest protection against pH change, when the following occurs? a. A strong acid is added to the solution. b. A strong base is added to the solution.

Unpolluted rain water has a pH of about 5.5. Acid rain has been shown to have a pH as low as 3.0. Calculate the [H+] ratio of acid rain to unpolluted rain.

12.62 Write the formula of the conjugate acid of each of the following bases, (a) OH-, (b) NHj, (c) CHjNHt, (d) HPO/-, (e) CO.,2’