Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Consider the synthesis of N,N-dimethyl-2-methylhexanamide from diethyl malonate. Fill in the best reagents to achieve this
synthetic transformation.
0=
Answer Bank
2 equiv. of (CH3)₂NH
1 equiv. of (CH3)₂NH
2-bromohexane
NaOEt, EtOH
BrCH₂CH₂CH₂CH₂
0=
SOCI₂
CH, Br
Na₂Cro
NaBH4, MeOH
NaOH, H₂O
H₂O*, heat
1.
2.
3.
4.
5.
6.
7.
8.
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Transcribed Image Text:Consider the synthesis of N,N-dimethyl-2-methylhexanamide from diethyl malonate. Fill in the best reagents to achieve this synthetic transformation. 0= Answer Bank 2 equiv. of (CH3)₂NH 1 equiv. of (CH3)₂NH 2-bromohexane NaOEt, EtOH BrCH₂CH₂CH₂CH₂ 0= SOCI₂ CH, Br Na₂Cro NaBH4, MeOH NaOH, H₂O H₂O*, heat 1. 2. 3. 4. 5. 6. 7. 8.
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