Biochemistry
9th Edition
ISBN: 9781319114671
Author: Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher: W. H. Freeman
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- Two solutions, 250.0 mL of 1.00 M CaCl2(aq) and 250.0 mL of 1.00 M K2SO4(aq), are combined, and the temperature decreased by 2.40 degrees C. Determine qrxn per mole of CaSO4(s) formed in the reaction. A) +12.0 kJ/mol B) -12.0 kJ/mol C) +6.00 kJ/mol D) -6.00 kJ/molarrow_forwardA 100.0 mL sample of 0.200 M aqueous hydrochloric acid is added to 100.0 ml of 0.200 M aqueous ammonia in a calorimeter whose heat capacity (excluding any water) is 480.0 J/K. The following reaction occurs when the two solutions are mixed. HCl(aq)+NH,(aq)—NH_Cl(aq) The temperature increase is 2.34 °C. Calculate AH per mole of HCI and NH, reacted. Select one: о a. -1.96 KJ/mol b. 154 KJ/mol O c. 485 KJ/mol d. 1.96 KJ/mol Jm e. -154 J/molarrow_forwardAt what pressure in atm does ethane (C₂H₆) have a density of 37.2 g/L at 75.0 °C?arrow_forward
- 1. The solubility of magnesium hydroxide (Mg(OH)2) is approximately 3.70 x10- M at room temperature. a. Write the aqueous dissolution ionic reaction for magnesium hydroxide. Include state symbols. b. Calculate the solubility product constant (Ksp) for magnesium hydroxide at room temperature. Refer back to the General Formula for “K" presented in the "Equilibrium Lab Manual" c. How many grams of magnesium hydroxide are present in 1.0 L of a saturated solution at room temperature?arrow_forwardHow many grams of potassium chlorate decompose to potassium chloride and 660. mL of O2 at 128. °C and 726. torr? Round your answer to 3 significant figures. 2KCIO3(s) 2KCI(s) + 302(g) Note: Reference the Conversion factors for non-SI units and Fundamental constants tables for additional information. g × Garrow_forwardCalculate AG for the reaction G+ H I + J when [G] = 0.0132 mM, [H] = 35.1 uM, [1] = 55.6 uM, [J] 18.7 uM, the temperature = 37 °C and AG°= -48.2 kJ/mol. Keep concentration units in uM. -50.3 kJ/mol -39.1 kJ/mol O-46 kJ/mol -25.8 kJ/molarrow_forward
- Draw the Mchelis Menton plot and the Line Weaver Burk Plot using the data given below and find the Vmax and Km from the Plot.arrow_forwardA 2.0% (by mass) aqueous solution of novocainium chloride (C13 H21 CIN2O2) freezes at -0.235 °C. a Calculate the van't Hoff factor, i. - Kp (H2O) = -1.86 °C/m. i = b How many moles of ions are in the solution per mole of compound? mol ionsarrow_forwardConsider the following reaction and its equilibrium constant: 12(g) 21(g) Kp = 0.209 atm A reaction mixture contains 0.89 atm 12 and 1.77 atm I. Which of the following statements is TRUE concerning this system?arrow_forward
- Consider the following reaction at 25°C with the ΔG°’ = +1800 J/mol for the forward reaction.The molar concentrations at the beginning of the reaction were [A] = 19 mM and [B] = 10 mM.After 1 hour, the concentrations were [A] = 16 mM and [B] = 13 mM. Calculate the ΔG of the reaction at the 1 hour timepoint. Please round to 1 decimal point.Gas constant = 8.315 J/mol Karrow_forwardNonearrow_forwardCalculate the equilibrium constant (K'eg) for each of the three reactions at pH 7.0 and 25 °C, using the AGʻ° values given. (a) glucose 6-phosphatase glucose 6-phosphate + H,O glucose + P; AG'° = –13.8 kJ/mol K'eq= (b) B-galactosidase lactose + H,O glucose + galactose AG'O = -15.9 kJ/mol K'eq=arrow_forward
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