Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter1: Gases And The Zeroth Law Of Thermodynamics
Section: Chapter Questions
Problem 1.15E: A 2.0 L soda bottle is pressurized with 4.5 atm of CO2 at 298 K. If the temperature is increased to...
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Question
The critical temperatures and pressures of a series of halogenated
methanes are as follows:(a) List the intermolecular forces that occur for each
compound. (b) Predict the order of increasing intermolecular
attraction, from least to most, for this series of
compounds. (c) Predict the critical temperature and pressure
for CCl4 based on the trends in this table. Look up
the experimentally determined critical temperatures and
pressures for CCl4, using a source such as the CRC Handbook
of Chemistry and Physics, and suggest a reason for any
discrepancies.
Transcribed Image Text:Compound
CCI,F
CCI,F2
CCIF3
CF4
Critical temperature (K)
471
385
302
227
Critical pressure (atm)
43.5
40.6
38.2
37.0
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