Compare the solubility of lead carbonate in each of the following aqueous solutions: Clear All 0.10 M Pb(NO3)2 More soluble than in pure water. 0.10 M K,CO3 Similar solubility as in pure water. 0.10 Μ ΝΗΝO, Less soluble than in pure water. 0.10 M NACH3C00
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- Compare the solubility of lead carbonate in each of the following aqueous solutions: Clear All 0.10 M Pb(CH3C00)2 More soluble than in pure water. 0.10 M (NH4)2CO3 Similar solubility as in pure water. 0.10 Μ KNΟS Less soluble than in pure water. 0.10 Μ ΝΗCH, COOCalculate the concentration of Y4-ion in 0.0100 M EDTA solution at pH 6. for pH 6, α4 = 2,2 x 10-5What mass of sodium glycolate (NaC2H3O3) should be added to 400.0 mL of 1.00 M glycolic acid to produce a buffer solution with a pH of 4.00? Ka = 1.47 x 10-4
- A water solution contains 60% Na2S202 together with 1% soluble impurity. Upon cooling to 10°C, Na2S202 • 5 H2O crystallizes out. The solubility of this hydrate is 1.4lb Na2S202 • 5 H20/lb free water. The crystals removed carry asadhering solution 0.06 lb solution/lb crystals. When dried to remove the remaining water (but not the water of hydration), the final dry Na2S202 5 H20 crystals must not contain more than 0.1% impurity. To meet this specification, the original solution, before cooling, is further diluted with water. On the basis of 100 Ib of the original solution,calculate (a) the amount of water added before cooling, and (b) the percentage recoveryof the Na2S202 in the dried hydrated crystalsCalculate the normality of a solution that contains 4.5 g of (COOH)2 in 3000 mL of solution? (Assume the (COOH)2 is to be completely neutralized in an acid-base * reaction.) 0.033 N O 0.33 N O 0.166 N O 0.0166 N 0.45 N O 0.045 N 000.0 OOA base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 88 of the manganese has precipitated? Table 5-7 Solubility-Product Constants, K, at 25°C Fluorides Chromates (cont.) Ag, Cro, PbCro, Hydroxides (cont) Ni(OH), Zn(OH), Cu(OH), Hg(OH), Sn(OH), Cr(OH), A(OH), BaF, MgF, PbF, SrF, CaF, 2.4 x 10-5 X 10-8 x 10-8 1.9 x 10-12 1.6 x 10-16 4.5 X 10-17 1.6 x 10-19 3 2 x 10-16 4 Carbonates 7.9 x 10-10 3.9 x 10-11 X 10-26 NiCO, CaCO, BaCo, SrCO, CuCO, ZnCO, MnCO, 1.4 x 10-7 3 10-27 4.7 x 10- 6.7 x 5 x 6 x 10-38 2.5 x 10-43 Chlorides 10-31 1.6 x 10- 1.7 x 10-10 1.1 x 10-18 1.6 x 10-9 7 x 10-10 2.5 x 10-10 10-33 PBCI, AgCi Hg,Cl, Fe(OH), Co(OH), Sulfides 2 x 10-10 8.8 x 10-11 2.1 x 10-11 Bromides X 10-16 X 10-19 3 x 10-21 X 10-22 2.5 x 10-22 X 10-26 1.0 x 10-28 MnS 7. PbBr, AgBr Hg, Br, 4.6 x 10-6 5.0 x 10-13 Feco Ag,CO, CdCo, PBCO, MgCO, Hg,CO, Fes 4 8.2 x 10-12 5.2 x 10-12 1.5 x 10-15 1 x 10-15 NiS 1.3 x 10-22 Cos ZnS lodides Pbl, Agl…
- 200 microliters of a standard solution of 0.200 mg/mL caffeine was mixed with 4.8 mL of 50 mM sodium phosphate buffer, pH 3: methanol (60:40 v/v). What is the concentration of caffeine, in mg/mL, in this solution? Give your answer to two significant figures.A base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 70 of the manganese has precipitated? Table 5-7 Solubility-Product Constants, K, at 25°C Fluorides Chromates (cont.) Ag, Cro, PbCro, Hydroxides (cont.) Ni(OH), Zn(OH), Cu(OH), Hg(OH)2 Sn(OH), Cr(OH), Al(OH), Fe(OH), Co(OH), Sulfides Baf, MGF2 PbF, SrF, CaF, 2.4 x 10-6 1.9 x 10-12 1.6 x 10-16 8 x 10-8 X 10-8 7.9 x 10-10 3.9 x 10-11 2 x 10-16 4.5 X 10-17 4 1.6 x 10-19 X 10-26 X 10-27 6.7 x 10-31 Carbonates NiCO, CaCO, BaCO, SrCO, CuCO, ZnCO, MNCO, FeCo, Ag,CO, CdCo, PbCO, M9CO, Hg,CO, 1.4 X 10-7 4.7 x 10-9 3. Chlorides 1.6 x 10-9 PbCl, AgCI Hg,Cl, х 10-33 X 10-38 2.5 x 10-43 1.6 x 10-5 X 10-10 2.5 x 10-10 2 x 10-1o 8.8 x 10-11 2.1 X 10-11 7 1.7 x 10-10 1.1 X 10-18 6. Bromides PbBr2 X 10-16 X 10-19 X 10-21 5 x 10-22 2.5 x 10-22 X 10-26 1.0 x 10-28 MnS 4.6 x 10-6 5.0 x 10-13 Fes 4. AgBr Hg,Br, 8.2 x 10-12 NiS Cos Zns 1.3 x 10-22 3 5.2 x 10-12 1.5 x 10-15 1 x 10-15 9.0 x 10-15…A 0.200 M solution of a weak monoprotic acid (HA) has a pH of 2.35. What is the value of K of this acid? a K =2.011e-4 a What is the percent ionization of this acid? Percent Ionization = .10 %
- Calculate the theoretical pH of a Tris buffer (pH 8.0) at 0 ºC. Assume that room temperature is 22 ºCAn aqueous solution contains 0.34 M potassium cyanide. One liter of this solution could be converted into a buffer by the addition of: (Assume that the volume remains constant as each substance is added.) 0.34 mol HCI04 0.16 mol NaOH 0.33 mol KCIO4 0.16 mol HCIO4 0.33 mol HCNYou just made a 1.5M permanganate solution. What concentration is your potassium permanganate solution in percent? "K: 39.10 g/mole" "Mn: 54.94 g/mole" "O: 16 g/mole" "MW of KMnO4 is 158.04 g/mole" O a. 0.24% Ob. 20.1% O c. 15.8% O d. 23.7% O e. 2%