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- Combustion of a fuel sample in a bomb calorimeter increases the temperature of the entire system by 5.10 °C if the calorimeter contains 1700 g of water, but only by 4.00 °C if the calorimeter contains 2200 g of water. What is the heat capacity of the dry bomb calorimeter assembly? Assume that the specific heat capacity of water is 4.18 J g–1 °C–1.What is the boiling point of 0.800 m lactose in water?(Kb for water is 0.512°C/m)°CA base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 88 of the manganese has precipitated? Table 5-7 Solubility-Product Constants, K, at 25°C Fluorides Chromates (cont.) Ag, Cro, PbCro, Hydroxides (cont) Ni(OH), Zn(OH), Cu(OH), Hg(OH), Sn(OH), Cr(OH), A(OH), BaF, MgF, PbF, SrF, CaF, 2.4 x 10-5 X 10-8 x 10-8 1.9 x 10-12 1.6 x 10-16 4.5 X 10-17 1.6 x 10-19 3 2 x 10-16 4 Carbonates 7.9 x 10-10 3.9 x 10-11 X 10-26 NiCO, CaCO, BaCo, SrCO, CuCO, ZnCO, MnCO, 1.4 x 10-7 3 10-27 4.7 x 10- 6.7 x 5 x 6 x 10-38 2.5 x 10-43 Chlorides 10-31 1.6 x 10- 1.7 x 10-10 1.1 x 10-18 1.6 x 10-9 7 x 10-10 2.5 x 10-10 10-33 PBCI, AgCi Hg,Cl, Fe(OH), Co(OH), Sulfides 2 x 10-10 8.8 x 10-11 2.1 x 10-11 Bromides X 10-16 X 10-19 3 x 10-21 X 10-22 2.5 x 10-22 X 10-26 1.0 x 10-28 MnS 7. PbBr, AgBr Hg, Br, 4.6 x 10-6 5.0 x 10-13 Feco Ag,CO, CdCo, PBCO, MgCO, Hg,CO, Fes 4 8.2 x 10-12 5.2 x 10-12 1.5 x 10-15 1 x 10-15 NiS 1.3 x 10-22 Cos ZnS lodides Pbl, Agl…
- Compare the solubility of lead carbonate in each of the following aqueous solutions: Clear All 0.10 M Pb(CH3C00)2 More soluble than in pure water. 0.10 M (NH4)2CO3 Similar solubility as in pure water. 0.10 Μ KNΟS Less soluble than in pure water. 0.10 Μ ΝΗCH, COOA water solution contains 60% Na2S202 together with 1% soluble impurity. Upon cooling to 10°C, Na2S202 • 5 H2O crystallizes out. The solubility of this hydrate is 1.4lb Na2S202 • 5 H20/lb free water. The crystals removed carry asadhering solution 0.06 lb solution/lb crystals. When dried to remove the remaining water (but not the water of hydration), the final dry Na2S202 5 H20 crystals must not contain more than 0.1% impurity. To meet this specification, the original solution, before cooling, is further diluted with water. On the basis of 100 Ib of the original solution,calculate (a) the amount of water added before cooling, and (b) the percentage recoveryof the Na2S202 in the dried hydrated crystalsA base is added to a 0.050 M solution of MnCl2, raising the pH gradually. Calculate the pH of the solution when 70 of the manganese has precipitated? Table 5-7 Solubility-Product Constants, K, at 25°C Fluorides Chromates (cont.) Ag, Cro, PbCro, Hydroxides (cont.) Ni(OH), Zn(OH), Cu(OH), Hg(OH)2 Sn(OH), Cr(OH), Al(OH), Fe(OH), Co(OH), Sulfides Baf, MGF2 PbF, SrF, CaF, 2.4 x 10-6 1.9 x 10-12 1.6 x 10-16 8 x 10-8 X 10-8 7.9 x 10-10 3.9 x 10-11 2 x 10-16 4.5 X 10-17 4 1.6 x 10-19 X 10-26 X 10-27 6.7 x 10-31 Carbonates NiCO, CaCO, BaCO, SrCO, CuCO, ZnCO, MNCO, FeCo, Ag,CO, CdCo, PbCO, M9CO, Hg,CO, 1.4 X 10-7 4.7 x 10-9 3. Chlorides 1.6 x 10-9 PbCl, AgCI Hg,Cl, х 10-33 X 10-38 2.5 x 10-43 1.6 x 10-5 X 10-10 2.5 x 10-10 2 x 10-1o 8.8 x 10-11 2.1 X 10-11 7 1.7 x 10-10 1.1 X 10-18 6. Bromides PbBr2 X 10-16 X 10-19 X 10-21 5 x 10-22 2.5 x 10-22 X 10-26 1.0 x 10-28 MnS 4.6 x 10-6 5.0 x 10-13 Fes 4. AgBr Hg,Br, 8.2 x 10-12 NiS Cos Zns 1.3 x 10-22 3 5.2 x 10-12 1.5 x 10-15 1 x 10-15 9.0 x 10-15…
- Compare the solubility of lead carbonate in each of the following aqueous solutions: Clear All 0.10 M Pb(NO3)2 More soluble than in pure water. 0.10 M K,CO, Similar solubility as in pure water. 0.10 M NH,NO3 Less soluble than in pure water. 0.10 M NACH3C00200 microliters of a standard solution of 0.200 mg/mL caffeine was mixed with 4.8 mL of 50 mM sodium phosphate buffer, pH 3: methanol (60:40 v/v). What is the concentration of caffeine, in mg/mL, in this solution? Give your answer to two significant figures.An aqueous antifreeze solution is 45.0% ethylene glycol () by mass. The density of the solution is 1.05. Calculate the molality, molarity, and mole fraction of the ethylene glycol
- A solution is made by dissolving 0.641 mol of nonelectrolyte solute in 763 g of benzene. Calculate the freezing point, T;, and boiling point, Tp, of the solution. Constants can be found in the table of colligative constants. %3D °C Tp = °C9. 3 μL of a 45 mM stock solution of a substrate is added to 8 mL of water. Calculate the following values. The substrate molecular weight is 125 g/mol. Substrate volume in mL Dilution factor Substrate number of moles Substrate concentration for the diluted solution in mM Substrate concentration for the diluted solution in mole/L Substrate concentration for the diluted solution in mg/mLIf your 16x concentrated stock solution contains 20g of NaCl per liter, how much Nacl would one liter of your working solution contain? Round your result to 2 decimal points. g of Nacl