Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Question

Propose a synthesis for the compounds below using the reagents below. 

Reagents (not necessarily a complete list): PCC 1. OsO4; 2. KHSO3 MsCl (or TsCI), pyridine 1. LIAIH4; 2. H3O+ NaH SOCI₂ TBDMS-CI or TMS-CI, Et3N 1. RSH, H+; 2. Raney Ni 1. Hg(O₂CCF3)2, ROH; 2. NaBH4 POCI3, pyridine PBr3 1. RMgX or RLİ; 2. H3O+ NaBH4 mCPBA CrO3, H₂SO4, H₂O H+, ROH NalO4 HX (X = Halogen) X₂ 1. Hg(OAc)2, H₂O; 2. NaBH4 1. H*, H₂NNH₂; 2. NaOH H₂, Lindlar's catalyst NaNHz 1. O3; 2. Zn, HOẠC 1. BH3-THF; 2. H₂O2, NaOH H₂, Pd/C 1. 03; 2. H₂O Na, NH3
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Transcribed Image Text:Reagents (not necessarily a complete list): PCC 1. OsO4; 2. KHSO3 MsCl (or TsCI), pyridine 1. LIAIH4; 2. H3O+ NaH SOCI₂ TBDMS-CI or TMS-CI, Et3N 1. RSH, H+; 2. Raney Ni 1. Hg(O₂CCF3)2, ROH; 2. NaBH4 POCI3, pyridine PBr3 1. RMgX or RLİ; 2. H3O+ NaBH4 mCPBA CrO3, H₂SO4, H₂O H+, ROH NalO4 HX (X = Halogen) X₂ 1. Hg(OAc)2, H₂O; 2. NaBH4 1. H*, H₂NNH₂; 2. NaOH H₂, Lindlar's catalyst NaNHz 1. O3; 2. Zn, HOẠC 1. BH3-THF; 2. H₂O2, NaOH H₂, Pd/C 1. 03; 2. H₂O Na, NH3
CI
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Transcribed Image Text:CI
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