Propose a synthesis for the compounds below using the reagents below. Reagents (not necessarily acomplete list):PCC1. OsO4; 2. KHSO3MsCl (or TsCI), pyridine1. LIAIH4; 2. H3O+NaHSOCI₂TBDMS-CI or TMS-CI, Et3N1. RSH, H+; 2. Raney Ni1. Hg(O₂CCF3)2, ROH; 2.NaBH4POCI3, pyridinePBr31. RMgX or RLİ; 2. H3O+NaBH4mCPBACrO3, H₂SO4, H₂OH+, ROHNalO4HX (X = Halogen)X₂1. Hg(OAc)2, H₂O; 2. NaBH41. H*, H₂NNH₂; 2. NaOHH₂, Lindlar's catalystNaNHz1. O3; 2. Zn, HOẠC1. BH3-THF; 2. H₂O2, NaOHH₂, Pd/C1. 03; 2. H₂ONa, NH3 CI

Reagent use: BH3, THF, H2O2, NaOH RMgX NaBH4…

Science

Chemistry

CI

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

Propose a synthesis for the compounds below using the reagents below.

Reagents (not necessarily a
complete list):
PCC
1. OsO4; 2. KHSO3
MsCl (or TsCI), pyridine
1. LIAIH4; 2. H3O+
NaH
SOCI₂
TBDMS-CI or TMS-CI, Et3N
1. RSH, H+; 2. Raney Ni
1. Hg(O₂CCF3)2, ROH; 2.
NaBH4
POCI3, pyridine
PBr3
1. RMgX or RLİ; 2. H3O+
NaBH4
mCPBA
CrO3, H₂SO4, H₂O
H+, ROH
NalO4
HX (X = Halogen)
X₂
1. Hg(OAc)2, H₂O; 2. NaBH4
1. H*, H₂NNH₂; 2. NaOH
H₂, Lindlar's catalyst
NaNHz
1. O3; 2. Zn, HOẠC
1. BH3-THF; 2. H₂O2, NaOH
H₂, Pd/C
1. 03; 2. H₂O
Na, NH3

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