Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Diol
In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl …
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Propose a synthesis for the compounds below using the reagents given below. 

### Reagents (not necessarily a complete list): - **PCC** - **1. OsO₄; 2. KHSO₃** - **MsCl (or TsCl), pyridine** - **1. LiAlH₄; 2. H₃O⁺** - **NaH** - **SOCl₂** - **TBDMS-Cl or TMS-Cl, Et₃N** - **1. RSH, H⁺; 2. Raney Ni** - **1. Hg(O₂CCF₃)₂, ROH; 2. NaBH₄** - **POCl₃, pyridine** - **PBr₃** - **1. RMgX or RLi; 2. H₃O⁺** - **NaBH₄** - **mCPBA** - **CrO₃, H₂SO₄, H₂O** - **H⁺, ROH** - **NaIO₄** - **HX (X = Halogen)** - **X₂** - **1. Hg(OAc)₂, H₂O; 2. NaBH₄** - **1. H⁺, H₂NNH₂; 2. NaOH** - **H₂, Lindlar’s catalyst** - **NaNH₂** - **1. O₃; 2. Zn, HOAc** - **1. BH₃-THF; 2. H₂O₂, NaOH** - **H₂, Pd/C** - **1. O₃; 2. H₂O** - **Na, NH₃** This list includes a variety of reagents commonly used in organic chemistry for different reactions such as oxidation, reduction, protection, and other transformations.
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Transcribed Image Text:### Reagents (not necessarily a complete list): - **PCC** - **1. OsO₄; 2. KHSO₃** - **MsCl (or TsCl), pyridine** - **1. LiAlH₄; 2. H₃O⁺** - **NaH** - **SOCl₂** - **TBDMS-Cl or TMS-Cl, Et₃N** - **1. RSH, H⁺; 2. Raney Ni** - **1. Hg(O₂CCF₃)₂, ROH; 2. NaBH₄** - **POCl₃, pyridine** - **PBr₃** - **1. RMgX or RLi; 2. H₃O⁺** - **NaBH₄** - **mCPBA** - **CrO₃, H₂SO₄, H₂O** - **H⁺, ROH** - **NaIO₄** - **HX (X = Halogen)** - **X₂** - **1. Hg(OAc)₂, H₂O; 2. NaBH₄** - **1. H⁺, H₂NNH₂; 2. NaOH** - **H₂, Lindlar’s catalyst** - **NaNH₂** - **1. O₃; 2. Zn, HOAc** - **1. BH₃-THF; 2. H₂O₂, NaOH** - **H₂, Pd/C** - **1. O₃; 2. H₂O** - **Na, NH₃** This list includes a variety of reagents commonly used in organic chemistry for different reactions such as oxidation, reduction, protection, and other transformations.
The image depicts a chemical reaction involving organic compounds. On the left side, there is a reactant: a benzene ring attached to a bromine atom (C6H5-CH2-Br), commonly referred to as benzyl bromide. The reaction is shown with a rightward arrow, indicating the transformation of the reactant into a product. On the right side, the product is shown: a benzene ring attached to a propyl group terminating in a methoxy group (C6H5-CH2-CH(CH3)-OCH3). This reaction suggests a substitution process where the bromine in benzyl bromide is replaced by a methoxypropyl group. The diagram does not include specific conditions or reagents necessary for the reaction, such as catalysts, solvents, temperature, or pressure, which are essential for carrying out the substitution.
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Transcribed Image Text:The image depicts a chemical reaction involving organic compounds. On the left side, there is a reactant: a benzene ring attached to a bromine atom (C6H5-CH2-Br), commonly referred to as benzyl bromide. The reaction is shown with a rightward arrow, indicating the transformation of the reactant into a product. On the right side, the product is shown: a benzene ring attached to a propyl group terminating in a methoxy group (C6H5-CH2-CH(CH3)-OCH3). This reaction suggests a substitution process where the bromine in benzyl bromide is replaced by a methoxypropyl group. The diagram does not include specific conditions or reagents necessary for the reaction, such as catalysts, solvents, temperature, or pressure, which are essential for carrying out the substitution.
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