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ASK
Science
Chemistry
Choose the thermodynamic product formed during the reaction depicted below. DBr tott Br A B Br C D OA OB Oc OD
Choose the thermodynamic product formed during the reaction depicted below. DBr tott Br A B Br C D OA OB Oc OD
BUY
Chemistry
10th Edition
ISBN:
9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
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1 Chemical Foundations
2 Atoms, Molecules, And Ions
3 Stoichiometry
4 Types Of Chemical Reactions And Solution Stoichiometry
5 Gases
6 Thermochemistry
7 Atomic Structure And Periodicity
8 Bonding: General Concepts
9 Covalent Bonding: Orbitals
10 Liquids And Solids
11 Properties Of Solutions
12 Chemical Kinetics
13 Chemical Equilibrium
14 Acids And Bases
15 Acid-base Equilibria
16 Solubility And Complex Ion Equilibria
17 Spontaneity, Entropy, And Free Energy
18 Electrochemistry
19 The Nucleus: A Chemist's View
20 The Representative Elements
21 Transition Metals And Coordination Chemistry
22 Organic And Biological Molecules
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Chapter Questions
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Problem 1RQ: What is a half-reaction? Why must the number of electrons lost in the oxidation half-reaction equal...
Problem 2RQ: Galvanic cells harness spontaneous oxidationreduction reactions to produce work by producing a...
Problem 3RQ: Table 17-1 lists common half-reactions along with the standard reduction potential associated with...
Problem 4RQ: Consider the equation G = -nF. What are the four terms in this equation? Why does a minus sign...
Problem 5RQ: The Nernst equation allows determination of the cell potential for a galvanic cell at nonstandard...
Problem 6RQ: What are concentration cells? What is in a concentration cell? What is the driving force for a...
Problem 7RQ
Problem 8RQ
Problem 9RQ: What characterizes an electrolytic cell? What is an ampere? When the current applied to an...
Problem 1ALQ
Problem 2ALQ: When balancing reactions in Chapter 3, we did not mention that reactions must be charge balanced as...
Problem 3ALQ: Sketch a galvanic cell, and explain how it works. Look at Figs. 17-1 and 17-2. Explain what is...
Problem 4ALQ: In making a specific galvanic cell, explain how one decides on the electrodes and the solutions to...
Problem 5ALQ
Problem 6ALQ
Problem 7ALQ: Sketch a cell that forms iron metal from iron(II) while changing chromium metal to chromium(III)....
Problem 8ALQ: Which of the following is the best reducing agent: F2, H2, Na, Na+, F? Explain. Order as many of...
Problem 9ALQ: You are told that metal A is a better reducing agent than metal B. What, if anything, can be said...
Problem 10ALQ: Explain the following relationships: G and w, cell potential and w, cell potential and G, cell...
Problem 11ALQ: Explain why cell potentials are not multiplied by the coefficients in the balanced redox equation....
Problem 12ALQ: What is the difference between and ? When is equal to zero? When is equal to zero? (Consider regular...
Problem 13ALQ: Consider the following galvanic cell: What happens to as the concentration of Zn2+ is increased? As...
Problem 14ALQ: Look up the reduction potential for Fe3+ to Fe2+. Look up the reduction potential for Fe2+ to Fe....
Problem 15ALQ: If the cell potential is proportional to work and the standard reduction potential for the hydrogen...
Problem 16ALQ: Is the following statement true or false? Concentration cells work because standard reduction...
Problem 17RORR: Define oxidation and reduction in terms of both change in oxidation number and electron loss or...
Problem 18RORR: Assign oxidation numbers to all the atoms in each of the following:...
Problem 19RORR: Specify which of the following equations represent oxidation reduction reactions, and indicate the...
Problem 20RORR: The Ostwald process for the commercial production of nitric acid involves the Following three steps:...
Problem 21RORR: Balance the following oxidation-reduction reactions that occur in basic solution using the...
Problem 22RORR: Balance the following oxidation-reduction reactions that occur in basic solution using the...
Problem 23Q: What is electrochemistry? What are redox reactions? Explain the difference between a galvanic and an...
Problem 24Q
Problem 25Q: When magnesium metal is added to a beaker of HCl(aq), a gas is produced. Knowing that magnesium is...
Problem 26Q: How can one construct a galvanic cell from two substances, each having a negative standard reduction...
Problem 27Q: The free energy change for a reaction, G, is an extensive property. What is an extensive property?...
Problem 28Q: What is wrong with the following statement: The best concentration cell will consist of the...
Problem 29Q: When jump-starting a car with a dead battery, the ground jumper should be attached to a remote part...
Problem 30Q: In theory, most metals should easily corrode in air. Why? A group of metals called the noble metals...
Problem 31Q: Consider the electrolysis of a molten salt of some metal. What information must you know to...
Problem 32Q: Consider the following electrochemical cell: a. If silver metal is a product of the reaction, is the...
Problem 33Q
Problem 34Q
Problem 35E: Consider the following galvanic cell: Label the reducing agent and the oxidizing agent, and describe...
Problem 36E: Consider the following galvanic cell: a. Label the reducing agent and the oxidizing agent, and...
Problem 37E: Sketch the galvanic cells based on the following overall reactions. Show the direction of electron...
Problem 38E: Sketch the galvanic cells based on the following overall reactions. Show the direction of electron...
Problem 39E: Calculate values for the galvanic cells in Exercise 37.
Problem 40E: Calculate values for the galvanic cells in Exercise 38.
Problem 41E: Sketch the galvanic cells based on the following half-reactions. Show the direction of electron...
Problem 42E: Sketch the galvanic cells based on the following half-reactions. Show the direction of electron...
Problem 43E: Give the standard line notation for each cell in Exercises 37 and41.
Problem 44E: Give the standard line notation for each cell in Exercises 38 and 42.
Problem 45E: Consider the following galvanic cells: For each galvanic cell, give the balanced cell equation and...
Problem 46E: Give the balanced cell equation and determine for the galvanic cells based on the following...
Problem 47E: Calculate values for the following g cells. Which reactions are spontaneous as written (under...
Problem 48E: Calculate values for the following cells. Which reactions are spontaneous as written (under standard...
Problem 49E: Chlorine dioxide (C1O2), which is produced by the reaction 2NaC1O2(aq)+Cl2(g)2ClO2(g)+2NaCl(aq) has...
Problem 50E: The amount of manganese in steel is determined by changing it to permanganate ion. The steel is...
Problem 51E: Calculate the maximum amount of work that can be obtained from the galvanic cells at standard...
Problem 52E: Calculate the maximum amount of work that can be obtained from the galvanic cells at standard...
Problem 53E: Estimate for the half-reaction 2H2O+2eH2+2OH given the following values of Gfo: H2O(l)=237kJ/mol...
Problem 54E: The equation G = nF also can be applied to half-reactions. Use standard reduction potentials to...
Problem 55E: Glucose is the major fuel for most living cells. The oxidative breakdown of glucose by our body to...
Problem 56E: Direct methanol fuel cells (DMFCs) have shown some promise as a viable option for providing green...
Problem 57E: Using data from Table 17-1, place the following in order of increasing strength as oxidizing agents...
Problem 58E: Using data from Table 17-1, place the following in order of increasing strength as reducing agents...
Problem 59E: Answer the following questions using data from Table 17-1 (all under standard conditions). a. Is...
Problem 60E: Answer the following questions using data from Table 17-1 (all under standard conditions). a. Is...
Problem 61E: Consider only the species (at standard conditions) Na+, Cl, Ag+, Ag, Zn2+, Zn, Pb in answering the...
Problem 62E
Problem 63E: Use the table of standard reduction potentials (Table 17-1) to pick a reagent that is capable of...
Problem 66E: Consider the concentration cell in Fig. 17-10. If the Fe2+ concentration in the right compartment is...
Problem 67E: Consider the concentration cell shown below. Calculate the cell potential at 25C when the...
Problem 68E: Consider a concentration cell similar to the one shown in Exercise 69, except that both electrodes...
Problem 69E: The overall reaction in the lead storage battery is Pb(s)+PbO2(s)+2H+(aq)+2HSO4(aq)2PbSO4(s)+2H2O(l)...
Problem 70E: Calculate the pH of the cathode compartment for the following reaction given = 3.01 V when [Cr3+] =...
Problem 71E: Consider the cell described below: Zn|Zn2+(1.00M)||Cu2+(l.00M)|Cu Calculate the cell potential after...
Problem 72E: Consider the cell described below: Al|Al3+(1.00M)||Pb2+(1.00M)|Pb Calculate the cell potential after...
Problem 73E: Calculate G and K at 25C for the reactions in Exercises 37 and 41.
Problem 74E: Calculate G and K at 25C for the reactions in Exercises 38 and 42.
Problem 75E: Consider the galvanic cell based on the following half-reactions: a. Determine the overall cell...
Problem 76E: Consider the galvanic cell based on the following half-reactions: a. Determine the overall cell...
Problem 77E: An electrochemical cell consists of a standard hydrogen electrode and a copper metal electrode. a....
Problem 78E
Problem 79E: An electrochemical cell consists of a standard hydrogen electrode and a copper metal electrode. If...
Problem 80E: An electrochemical cell consists of a nickel metal electrode immersed in a solution with [Ni2+] =...
Problem 81E: Consider a concentration cell that has both electrodes made of some metal M. Solution A in one...
Problem 82E: You have a concentration cell in which the cathode has a silver electrode with 0.10 M Ag+. The anode...
Problem 83E: Under standard conditions, what reaction occurs, if any, when each of the following operations is...
Problem 84E: A disproportionation reaction involves a substance that acts as both an oxidizing and a reducing...
Problem 85E: Consider the following galvanic cell at 25C: Pt|Cr2+(0.30M),Cr3+(2.0M)||Co2+(0.20M)|Co The overall...
Problem 86E: An electrochemical cell consists of a silver metal electrode immersed in a solution with [Ag+] = 1.0...
Problem 87E: Cadmium sulfide is used in some semiconductor applications. Calculate the value of the solubility...
Problem 88E: For the following half-reaction, = 2.07 V: A1F63(aq)+3eAl(s)+6F(aq) Using data from Table 17-1,...
Problem 89E: Calculate for the following half-reaction: AgI(s)+eAg(s)+I(aq) (Hint: Reference the Ksp value for...
Problem 90E: The solubility product for CuI(s) is 1.1 102 Calculate the value of for the half-reaction...
Problem 91E: How long will it take to plate out each of the following with a current of 100.0 A? a. 1.0 kg AI...
Problem 92E: The electrolysis of BiO+ produces pure bismuth. How long would it take to produce 10.0 g Bi by the...
Problem 93E: What mass of each of the following substances can be produced in 1.0 h with a current of 15 A? a. Co...
Problem 94E: Aluminum is produced commercially by the electrolysis of Al2O3 in the presence of a molten salt. If...
Problem 95E: Electrolysis of an alkaline earth metal chloride using a current of 5.00 A for 748 s deposits 0.471...
Problem 97E: What volume of F2 gas, at 25C and 1.00 atm, is produced when molten KF is electrolyzed by a current...
Problem 98E: What volumes of H2(g) and O2(g) at STP are produced from the electrolysis of water by a current of...
Problem 99E: A single HallHeroult cell (as shown in Fig. 17-22) produces about 1 ton of aluminum in 24 h. What...
Problem 100E: A factory wants to produce 1.00 103 kg barium from the electrolysis of molten barium chloride. What...
Problem 101E: It took 2.30 min using a current of 2.00 A to plate out all the silver from 0.250 L of a solution...
Problem 102E: A solution containing Pt4+ is electrolyzed with a current of 4.00 A. How long will it take to plate...
Problem 103E: A solution at 25C contains 1.0 M Cd2+, 1.0 M Ag+, 1.0 M Au3+, and 1.0 M NiH2+ in the cathode...
Problem 104E: A solution at 25C contains 1.0 M Cu2 and 1.0 104 M Ag+. Which metal will plate out first as the...
Problem 105E: In the electrolysis of an aqueous solution of Na2SO4, what reactions occur at the anode and the...
Problem 106E: Copper can be plated onto a spoon by placing the spoon in an acidic solution of CuSO4(aq) and...
Problem 107E
Problem 108E
Problem 109E: What reactions take place at the cathode and the anode when each of the following is electrolyzed?...
Problem 110E: What reaction will take place at the Cathode and the anode when each of the following is...
Problem 111AE: The saturated calomel electrode. abbreviated SCE. is often used as a reference electrode in making...
Problem 112AE: Consider the following half-reactions: Explain why platinum metal will dissolve in aqua regia (a...
Problem 113AE: Consider the standard galvanic cell based on the following half-reactions: Cu2++2eCuAg++eAg The...
Problem 114AE: A standard galvanic cell is constructed so that the overall cell reaction is...
Problem 115AE: The black silver sulfide discoloration of silverware can be removed by heating the silver article in...
Problem 116AE
Problem 117AE: When aluminum foil is placed in hydrochloric acid, nothing happens for the first 30 seconds or so....
Problem 118AE
Problem 119AE
Problem 120AE
Problem 121AE: A fuel cell designed to react grain alcohol with oxygen has the following net reaction:...
Problem 122AE: The overall reaction and equilibrium constant value for a hydrogen-oxygen fuel cell at 298 K is...
Problem 123AE
Problem 124AE: The overall reaction and standard cell potential at 25C for the rechargeable nickel-cadmium alkaline...
Problem 125AE
Problem 126AE: The ultimate electron acceptor in the respiration process is molecular oxygen. Electron transfer...
Problem 127AE: One of the few industrial-scale processes that produce organic compounds electrochemically is used...
Problem 128AE: It took 150. s for a current of 1.25 A to plate out 0.109 g of a metal from a solution containing...
Problem 129AE
Problem 130AE: In the electrolysis of a sodium chloride solution, what volume of H2(g) is produced in the same time...
Problem 131AE: An aqueous solution of an unknown salt of ruthenium is electrolyzed by a current of 2.50 A passing...
Problem 132CWP: Which of the following statement(s) is/are true? a. Copper metal can be oxidized by Ag+ (at standard...
Problem 133CWP: Consider a galvanic cell based on the following half-reactions: a. What is the expected cell...
Problem 134CWP
Problem 135CWP: Consider a galvanic cell based on the following half-reactions: a. What is the standard potential...
Problem 136CWP: An electrochemical cell consists of a silver metal electrode immersed in a solution with [Ag+] =...
Problem 137CWP: An aqueous solution of PdCl2 is electrolyzed for 48.6 seconds, and during this time 0.1064 g of Pd...
Problem 138CP: Consider the following half-reactions:...
Problem 139CP: Consider the following reduction potentials: Co3++ 3e Co = 1.26 V Co2++ 2e Co = 0.28 V a. When...
Problem 140CP: Calculate and G for the reaction 2H2O(l) 2H2(g) + O2(g) at 298 K. Using thermodynamic data in...
Problem 141CP
Problem 142CP: The overall reaction in the lead storage battery is Pb(s)+PbO2(s)+2H+(aq)+2HSO4(aq)2PbSO4(s)+2H2O(l)...
Problem 143CP: Consider the following galvanic cell: Calculate the KSP value for Ag2SO4(s). Note that to obtain...
Problem 144CP: A zinc-copper battery is constructed at follows at 25C: Zn|Zn2+(0.10M)||Cu2+(2.50M)|Cu The mass of...
Problem 145CP: A galvanic cell is based on the following half-reactions: where the iron compartment contains an...
Problem 146CP: Consider a cell based on the following half-reactions: a. Draw this cell under standard conditions,...
Problem 147CP
Problem 148CP: You have a concentration cell with Cu electrodes and [Cu2+] = 1.00 M (right side) and 1.0 104M...
Problem 149CP: A galvanic cell is based on the following half-reactions: In this cell, the silver compartment...
Problem 150CP: Given the following two standard reduction potentials, solve for the standard reduction potential of...
Problem 151CP: Consider the following galvanic cell: Calculate the concentrations of Ag+(aq) and Ni2+(aq) once the...
Problem 152CP
Problem 153CP: Consider the following galvanic cell: A 15 0-mole sample of NH is added to the Ag compartment...
Problem 154CP: When copper reacts with nitric acid, a mixture of NO(g) and NO2(g) is evolved. The volume ratio of...
Problem 155IP: The following standard reduction potentials have been determined for the aqueous chemistry of...
Problem 156IP: An electrochemical cell is set up using the following unbalanced reaction: Ma+(aq)+N(s)N2+(aq)+M(s)...
Problem 157IP: Three electrochemical cells were connected in series so that the same quantity of electrical current...
Problem 158IP: A silver concentration cell is set up at 25C as shown below: The AgCl(s) is in excess in the left...
Problem 159MP: A galvanic cell is based on the following half-reactions: In this cell, the copper compartment...
Problem 160MP: The table below lists the cell potentials for the 10 possible galvanic cells assembled from the...
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Choose the thermodynamic product formed during the reaction depicted below. DBr tott Br A B Br C D OA OB Oc OD
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Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
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9781305079243
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