Briefly explain the electronic effect of the subsistent present in your acid compared to benzoic acid

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter17: Applications Of Infrared Spectrometry
Section: Chapter Questions
Problem 17.6QAP
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Benzoic Acid 

V end point = 22 ml of NaOH

V 1/2 = 11 ml of NaOH 

pKa = 5

Substituted Acid - P- bromobenzoic Acid 

V end point = 17 ml of NaOH

V 1/2 = 8.5 ml of NaOH 

pKa = 4.9

Briefly explain the electronic effect of the subsistent present in your acid compared to benzoic acid 

 

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