Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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4:25 1
ull 5G D
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Be sure to answer all parts.
Hint
The American chemist Robert S. Mulliken suggested a different
definition for the electronegativity (EN) of an element, given by
IE,
Solution
Element
EA
kJ/mol kJ/mol
Guided Solution
IE, + EA
EN =
1314
141
2
1680
328
where IE, is the first ionization energy and EA is the electron affinity of
CI
1256
349
the element.
Calculate the electronegativities of O, F, and Cl using the preceding equation and the data in the
table.
EN(O) =
kJ/mol
EN(F) =
kJ/mol
EN(CI) =
kJ/mol
Determine the electronegativities of these elements on the Mulliken and Pauling scales. (To convert to
the Pauling scale, divide each EN value by 230 kJ/mol.)
Mulliken EN(F)
Mulliken EN(CI)
Mulliken EN(0)
Pauling scale =
Pauling scale =
Pauling scale =
(Pauling EN(CI) = 3.0)
(Pauling EN(O) = 3.5)
(Pauling EN(F) = 4.0)
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Transcribed Image Text:4:25 1 ull 5G D Send a chat Be sure to answer all parts. Hint The American chemist Robert S. Mulliken suggested a different definition for the electronegativity (EN) of an element, given by IE, Solution Element EA kJ/mol kJ/mol Guided Solution IE, + EA EN = 1314 141 2 1680 328 where IE, is the first ionization energy and EA is the electron affinity of CI 1256 349 the element. Calculate the electronegativities of O, F, and Cl using the preceding equation and the data in the table. EN(O) = kJ/mol EN(F) = kJ/mol EN(CI) = kJ/mol Determine the electronegativities of these elements on the Mulliken and Pauling scales. (To convert to the Pauling scale, divide each EN value by 230 kJ/mol.) Mulliken EN(F) Mulliken EN(CI) Mulliken EN(0) Pauling scale = Pauling scale = Pauling scale = (Pauling EN(CI) = 3.0) (Pauling EN(O) = 3.5) (Pauling EN(F) = 4.0)
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