Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- Draw a structural formula for the more stable carbocation intermediate formed in the reaction shown. CHCH3 HBr • You do not have to consider stereochemistry. • Do not include anionic counter-ions, e.g., I', in your answer. • For cases in which carbocations of the same or similar stability are expected, draw all of the structures. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. C. Adpo ChemDoodle (Previous Next Email Instructor Save andarrow_forward5. Synthesis a) Show how to make the following ether starting from Propylchloride and 2-lodopropane, keep in mind that secondary alkyl halides eliminate with nucleophiles that are strong bases to give you the alkene products. CIarrow_forwardThis is the general mechanism of nucleophilic addition of aldehydes and ketones. Nu: Nu- H-Nu Nu-Ċ-0-H + Nu: Represent the mechanism with the energy diagram showing the transition states and the intermediate.arrow_forward
- #6). Second picture shows instructions on how the arrows must be shown as.arrow_forwardDraw the products of the two step reaction sequence shown below. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers. Ignore inorganic byproducts. НО. 1. NaCN 2. H₂O OH ………. Select to Edit Qarrow_forwardH2SO4 CH3CH2OH a. Draw the structure of the tetrahedral intermediate INITIALLY FORMED in the reaction shown. • You do not have to consider stereochemistry. • Do not include counter-ions, e.g., Na", I', in your answer. • In cases where there is more than one answer, just draw one. ору astearrow_forward
- Substitution and elimination: predict the product Maximum allowed tries per question: Unlimited (7) Draw the major organic product of the reaction. Follow this procedure: determine whether the reaction conditions are acidic or basic; identify the most nucleophilic/basic atom, the electrophilic atom, and the leaving group; predict whether elimination or substitution will occur; and then draw the product. Indicate the stereochemistry at every stereocenter with a single wedged (up), hashed (down), or wavy (a mixture of up and down; either) bond. Launch MarvinJSTM viewer or click image to copy source CH3 H3C EtONa EtOH Brarrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting structure, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Then draw any missing organic intermediates or products for this reaction. Include all lone pairs in the structures. Ignore inorganic byproducts and counterions. H 0:0- HsC H Select to Add Arrows H HaC Select to Add Arrows CH₂OH, H CH3OH, H* CH3OH, H* HaC H Select to Add Arrows 1 CH3OH, H+ HaC H H Select to Add Arrows Iarrow_forwardFor the dehydration shown, use curved arrows to show the formation of the carbocation intermediate in the presence of sulfuric acid H, SO,, then draw the structures of the minor and major products of the elimination. 4 H2SO4 Major and Minor products HO: The H, SO, is abbreviated as H* in the drawing module. Do not delete any pre-drawn bonds, charges, or lone pairs. If you 4 accidentally make a mistake, remove the last change by using the undo button on the lower left or revert the drawing palette to the original state by selecting the More menu, then select Reset Drawing. Step 1: Use curved arrows to complete the Step 2: Use a curved arrow to show the protonation mechanism of the alcohol. formation of the carbocation intermediate for the elimination. Select Draw Rings More Erase Select Draw Rings More Erase C H +H, SO, : OH он,arrow_forward
- Draw the major product of this reaction. Include stereochemistry if applicable. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, where applicable. Ignore byproducts. Br H2O heat Drawingarrow_forwardSubstitution and elimination: predict the product Maximum allowed tries per question: Unlimited (3) Draw the major organic product of the reaction. Follow this procedure: determine whether the reaction conditions are acidic or basic; identify the most nucleophilic/basic atom, the electrophilic atom, and the leaving group; predict whether elimination or substitution will occur; and then draw the product. Indicate the stereochemistry at every stereocenter with a single wedged (up), hashed (down), or wavy (a mixture of up and down; either) bond. Launch MarvinJSTM viewer or click image to copy source H₁₂C CH3 EtOH Brarrow_forwardcurved arrows are used to show the flow of electrons. follow the curved arrows and draw the structure of the missing intermediates and products in the following mechanism. include all lone pairs and charges. ignore stereochemistry. ignore inorganic byproducts.arrow_forward
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