CH3||CH3H₂OH2SO4CH3CHCH2CH2C—ОCH₂CH₂CHCH3a. Draw the structure of the tetrahedral intermediateINITIALLY-FORMED in the reaction shown.•••You do not have to consider stereochemistry.Do not include counter-ions, e.g., Na+, I, in youranswer.In cases where there is more than one answer, justdraw one.√n [ChemDoodleⓇb. Draw the structures of the organic products of the acyltransfer reaction.•You do not have to consider stereochemistry.Draw the neutral form of the products; no charges.Draw one structure per sketcher. Add additional

Esters on hydrolysis yield alcohol and carboxylic acid. Hydrolysis takes place in the presence of an…

Answered: a. Draw the structure of the…

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a. Draw the structure of the tetrahedral intermediate INITIALLY-FORMED in the reaction shown.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter24: Catalytic Carbon-carbon Bond Formation

Section: Chapter Questions

Problem 24.8P

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Question

CH3
||
CH3
H₂O
H2SO4
CH3CHCH2CH2C—ОCH₂CH₂CHCH3
a. Draw the structure of the tetrahedral intermediate
INITIALLY-FORMED in the reaction shown.
•
•
•
You do not have to consider stereochemistry.
Do not include counter-ions, e.g., Na+, I, in your
answer.
In cases where there is more than one answer, just
draw one.
√n [
ChemDoodle
Ⓡ
b. Draw the structures of the organic products of the acyl
transfer reaction.
•
You do not have to consider stereochemistry.
Draw the neutral form of the products; no charges.
Draw one structure per sketcher. Add additional

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Step 1: Acid catalyzed ester hydrolysis

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Step 2: Formation of the initially formed tetrahedral intermediate

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Step 3: Determining the acyl transfer product

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