A simplified version of the computed energy profile for the Wittig reaction of a stabilised ylide that we saw in the Introduction is shown below, with energy differences in kJ mol¹¹. Ph 120 OMe Ald + Ylide 42 Ph k₁ Oxaphosphetane (OP) K-1 24 OP CO₂Me that k_₂ 200 Ph CO₂Me Alk + Oxide Remember that rate constants k are related to activation energies E₂: k = Ae-Ea/RT (R = 0.00831 kJ mol-¹ K-¹) 1. Which is the rds? 2. Predict the rate equation. 3. Assuming that the A values for the steps are all 10¹0, calculate the rate constants k₂, k.₁, k₂ and k.₂ at 350 K. 4. Is the 2nd step reversible at 350 K?

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Chapter11: Chemical Kinetics
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Problem 11.33PAE: The following experimental data were obtained for the reaction of \'I14* and NOf in acidic solution....
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A simplified version of the computed energy profile for the Wittig reaction of a stabilised ylide that
we saw in the Introduction is shown below, with energy differences in kJ mol¹¹.
120
Pa
Ph
OMe
Ald + Ylide
42
Ph
K-1
24
Oxaphosphetane
(OP)
OP
CO₂Me
at that
200
Ph
CO₂Me
Alk + Oxide
Remember that rate constants k are
related to activation energies E₂:
k = Ae-Ea/RT (R = 0.00831 kJ mol-¹ K-¹)
1. Which is the rds?
2. Predict the rate equation.
3. Assuming that the A values for the
steps are all 10¹0, calculate the rate
constants k₁, k.₁, k₂ and k.₂ at 350 K.
4. Is the 2nd step reversible at 350 K?
Transcribed Image Text:A simplified version of the computed energy profile for the Wittig reaction of a stabilised ylide that we saw in the Introduction is shown below, with energy differences in kJ mol¹¹. 120 Pa Ph OMe Ald + Ylide 42 Ph K-1 24 Oxaphosphetane (OP) OP CO₂Me at that 200 Ph CO₂Me Alk + Oxide Remember that rate constants k are related to activation energies E₂: k = Ae-Ea/RT (R = 0.00831 kJ mol-¹ K-¹) 1. Which is the rds? 2. Predict the rate equation. 3. Assuming that the A values for the steps are all 10¹0, calculate the rate constants k₁, k.₁, k₂ and k.₂ at 350 K. 4. Is the 2nd step reversible at 350 K?
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