A 0.693 g0.693 g sample of a metal, M, reacts completely with sulfuric acid according to   M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g)M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g)   A volume of 269 mL269 mL of hydrogen is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 756.0 Torr, and the temperature is 25 °C. The vapor pressure of water at 25 °C is 23.8 Torr. Calculate the molar mass of the metal.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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A 0.693 g0.693 g sample of a metal, M, reacts completely with sulfuric acid according to

 

M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g)M(s)+H2SO4(aq)⟶MSO4(aq)+H2(g)

 

A volume of 269 mL269 mL of hydrogen is collected over water; the water level in the collecting vessel is the same as the outside level. Atmospheric pressure is 756.0 Torr, and the temperature is 25 °C. The vapor pressure of water at 25 °C is 23.8 Torr. Calculate the molar mass of the metal.

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This question is answered by using the simple concept of stoichiometry which involves the relationship between moles of reactants and products using balanced chemical equation. Firstly using the ideal gas equation, moles of hydrogen gas are calculated then molar mass of metal is calculated.

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