A (a) Draw the structures of the species that correspond to each of the peaks A-E in the following mass spectrum of heptane. (b) Identify the M* peak, the M + 1 peak, and the base peak. 100 80 – 60 40 20 D 20 40 60 80 100 120 m/z Relative abundance
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![A
(a) Draw the structures of the species that correspond
to each of the peaks A-E in the following mass
spectrum of heptane. (b) Identify the M* peak, the
M + 1 peak, and the base peak.
100
80 –
60
40
20
D
20
40
60
80
100
120
m/z
Relative abundance](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F5c812b09-6078-42f6-ace0-ea08222e14c4%2F1e3003a1-162d-4075-a544-ddfaf16c1f0f%2Fjrwtbml.png&w=3840&q=75)
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- Consider the mass spectrum below. 100 80- 60- 20 0.0- 0.0 60 100 miz SDBS, National Institute of Advanced Industrial Science and Technology Which peak is the molecular ion? Choose one OA OB OD. OG8. a) Use the mass spectrum to determine the identity of the halogen atom (X) in the following molecular formula. 100 - C3H5XO2 80- 60 40 20- 152 154 20 40 60 80 100 120 140 160 180 200 m/z Relative Intensity30. (6) Determine four molecular formulas for a compound with a mass spectrum of 180: 182 (M: M+2) in a 3:1 ratio. (b) Calculate DBEs for each formula.
- Assign molecules A, E, G, and H to the correct mass spectrum and provide the structure of thebase peak.Although 2,2-dimethylhexane has a molecular weight of 114, no peak is observed at m/z = 114. The base peak in the mass spectrum occurs at M-57 (a) Draw the fragmentation responsible for the formation of M-57 ion (b) Explain why this cation is the most abundant ion to pass through the spectrometer. (c) Explain why no molecular ion survive long enough to be detected. (d) Can you offer an explanation as to why M-15 peak is not the base peak?A compound gives a mass spectrum with essentially only three peaks at m/z = 77 (40%), 112 (100%), and 114 (33%). Identify the compound.
- Butane, C4H10, would have which of the following fragments in its mass spectrum? m/z | 15 II 29 III 57 1) | 2) || 3) |II1. The EI-MS of methylcyclohexane is shown below. Locate the following information in it: CH3 (a) The molecular ion. (b) The base peak. (c) The Mt - C3H7 fragment ion. 83 100 55 80 60 98 40 27 69 20 60 70 80 90 100 20 30 40 50Identify the fragment giving rise to the peak at m/z 43.
- 42) Determine the mass of the likely fragment ion that will be observed in the mass spectrum for following molecule H CH;CH;CH;CH; N-CH;CH,On each mass spectrum above, indicate the base peak and the molecular ion peak (or at least where you would expect to find it) and if the base peak on the mass spectrum for linalool has m/z 71, propose a structure for this fragment ion.The base peak in the mass spectrum of propanone (acetone) occurs at m/z 43. What cation does this peak represent?
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