
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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A mass spec of a compound gave M+ peak at 118 of 57.7% of the base peak. It also had a peak at 120 of 2.6% of the base peak. This compound includes?
A) S
B) Br
C) Cl
D) P
E) N
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- 4arrow_forwardPropose a molecular formula for a compound that exhibits the given peaks in its mass spectrum. Draw a possible structure. M*• at m/z = 136, relative height = 12.1% (M+1)*• at m/z = 137, relative height = 1.2%arrow_forwardWhich one is the incorrect statement regarding mass spectrum? Question 25 options: In case of alcohols, M-18 peak is produced due to the loss of neutral H2O molecule (Dehydration) The relative heights of (M)+• peak and (M+1)+• peak is used to calculate the number of carbon atoms The structure likely contains a bromine atom if the (M+2)+• peak and (M)+• are almost similar in heights The molecular ion peak (M)+• always represent the base peak The structure likely contains a chlorine atom if the (M+2)+• peak is approximately one-third as tall as (M)+•arrow_forward
- Which C-H bonds are responsible for the following peaks/signals? C6H1202 s are Peak A = Peak B= Peak C= Enter 12 if a H is not labeled that created the peak/signal. this peak disappears with the addition of D20 By PPMarrow_forwardGiven the parent compound, draw the mass spectrum fragment that is observed at m/z 43. Draw the fragment. Include hydrogen atoms and the positive charge. Select ✓ Draw C Rings H More Erase Q2 Qarrow_forwardThe mass spectrum for acetophenone is shown below. a) Where does the molecular ion show up? ?) b) Which peak is the base peak? ? 1) The mass spectrum for acetophenone is shown below. Relative Intensity 100- 80- 20- acetophenone 0-tyttim 20 10 30 40 50 60 77 trommlilily 70 m/z 80 90 100 105 Ć 110 120 120 a) Where does the molecular ion show up? (m/z = ?) b) Which peak is the base peak? (m/z = ?) c) Draw the structure of the charged species responsible for the peak at m/z = 120. d) Draw the structure of the charged species responsible for the peak at m/z = 105. e) Draw the structure of the charged species responsible for the peak at m/z = 77.arrow_forward
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