9.34. Assign the chemical shifts and splitting patterns to specific aspects of the structure you propose. C5H12O 1H 2H 2 6H ille H(ppm) 1 3H и 0
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- What is structure? Formula is C7H12O47. Consider the C=O stretching data for the following cyclic ketones: cyclopropane 1813 cm³¹; cyclobutanone 1791 cm³¹; cyclopentanone 1740 cm³¹. (a) which ketone has the strongest bond? (b) where in the trend would you expect the C=O stretch of cyclopropenone? (Use the hybridization information in the same way we used hybridization for C-H stretching.)10. Determine the structures of each compound with the given information. A) CsH12 2.0 1.2 1.8 LEO 40 1.5 160 30 140 1.4 1.20 1.2 100 20 B) C4H6O4 IR Data (format= shape of peak, intensity of peak): 3420 cm' (broad, med.), 2932 cm (broad, strong), 1695 cm (narrow, strong), 1419 cm¹ (narrow, med.), 1311 cm (narrow, med.), 1203 cm' (narrow, strong), and a few other weak peaks between 924- 638 cm¹. 1.0 BO Mu 0.8 10 1 0.5 Soivent 0 www.qq.cong 20
- 3. Predict the spectral features for the following isomers of C4H8O and match each structure to a spectrum below. 요 요 10 11 10 4 0Which of the folowing molecules wil not display an Infrared spectrum? Br Co, HCECH Benzene CS TOSHISA F7 F8 F1 F12 & E5 6 1 7 v 8 A9 9 0Predict the splitting pattern for each kind of hydrogen in isopropyl propanoate, CH3CH2CO2CH(CH3)2.
- 8. Which of the following pairs of compounds is likely to absorb radiation at the longer wavelength and with greater intensity? (a) CH3CH2CO₂H or CH2=CHCO₂H (b) CH3CH=CHCH=CHCH3 or CH3C = C—C = CCH3 OCH3 (c) or CH3what structure would be represented HNMR with a singlet at 7.29 being caused by 2 hydrogens and a doublet at 3.88 being caused by 9 hydrogens?1. Draw two constitutional isomers of the formula C6H11B1. Explain how you would differentiate those molecules using either spectroscopy or spectrometry. You only need to differentiate them using one example.
- 1. Draw all possible isomers for the molecular formula C6H14 Next predict mass spectra of all isomers and explain how you would use mass spectra to identify each of the isomers.A molecule with the molecular formula of C6H100 produces the IR spectrum shown below. Draw a structure that best fits this data. 0OSL 000 DO0S Wavenurmbers (cm')What is the structure of the compound in Spec. 1? Would ethylene oxide be a reasonable answer? 8 S SPEC 0 C₂4.0