5. What is the product, if butyrolactone is first reacted. with lithium aluminum deuteride, then the reaction mixture is worked up using aqueous hydrochloric acid? I need the mechanism and work up drawn
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- Draw the principal organic product for the reaction when 2-bromopropane is treated with lithium in diethyl ether, followed by copper(I) iodide and then 1-bromobutane. Click and drag to start drawing a structure. B moleced_edit Am toA Moving to another question will save this response. Question 3 Which of the following statements about ethanethiol (CH3CH2SH) is(are) correct? O Ethanethiol will be effectively converted into its conjugate base through a reaction with sodium hydroxide (NAOH) O Ethanethiol is a good nucleophile which could react with a 1° alkyl halide in an SN2 reaction to produce a sulfide (thioether) O Ethanethiol can undergo oxidation by reaction with KMNO4 to produce a sulfonic acid O Statements 1 and 2 are correct O All of the statements are correct A Moving to another question will save this response. 080 acer FS F65. Write a flow chart to show how you could separate the following pairs of compounds by using acid-base extraction. a) fluorenone and p-bromobenzoic acid do b) p-nitrophenol and p-bromobenzoic acid HO NO₂ c) p-aminobenzoic acid and p-bromobenzoic acid H₂N Br OH يوم vol ob OH Br OH & OH
- Identify the reactions needed to prepare A) (1) Acetyl chloride, (2) LIAIH4, (3) Benzyl bromide B) (1) Benzaldehyde/NaBH3CN, (2) Formaldehyde/ NaBH3CN C) (1) Methyl iodide, (2) Acetyl chloride, (3) LIA|H4 D) (1) Benzyl bromide, (2) NaBH3CN N-benzyl-N-methylbutylamine from 1-aminobutane?d. Retrosynthetic Analysis: Forward Reaction: 2 stepsTreatment of acetylene with a suitable base affords lithium acetylide, which was used as a reagent in a partial synthesis of the antitumor natural product (+)-acutiphycin. (Org. Lett. 2014, 16, 1168-1171) Possible bases to consider H-C=C-H Acetylene Step 1 Li :Base T H-O: Li Lithium hydroxide (LiOH) three steps Lithium acetylide Draw the structure of lithium acetylide. Draw Your Solution di. Η Η Η Η | | | | H-C-C-C-C: II HH HH Butyllithium (BuLi) OR CEC- Li OH CH3 -H CH3 Lithium diisopropyl amide (LDA) OMe H3C H H₂C many steps Li HO OH I (+)-Acutiphycin CH3 CH₂ "OH
- 1. Show the products of the reductive amination reactions below; a) Acetone + NH3, followed by H2/Ni2 b) Acetone + CH3NH2, followed by LIBH3CN c) Acetone + (CH3)2NH, followed by LIBH3CN 2. Write the reaction and the names of the products formed in the reaction of aniline and N-methylaniline with: a) NaNO3+HCI followed by CuClI b) NaNO3+HCI followed by Cu20, Cu2*, H202 Question: a) Show the mechanism of synthesis of an amide from an ester and a primary amine: b) The ester responsible for the aroma of the rum has the following structural formula: CH3 H-C-CH2-0-C-CH3 || CH3 Write down the complete chemical reaction (detailed mechanism) that makes it possible to obtain the ester described above, starting from the carboxylic acid (use SOCI, to obtain the acyl chloride).aching and G how many valence electrons d X lewis sturctures with copper - inment/takeCovalentActivity.do?locator=assignment-take [Review Topics) [References) Draw structural formulas for the a,B-unsaturated aldehyde or ketone and the lithium diorganocuprate (Gilman reagent) that could be used in a synthesis of the compound shown below. CH3 H O. You do not have to consider stereochemistry. In cases where there is more than one answer, just give one. If a structure has a copper-lithium bond, draw the lithium ion in a separate sketcher. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple reactants using the + sign from the drop-down menu. ChemDoodle Previous Next Email Instructor Save and Exit Cengage Learning | Cengage Technical Support MacBook Pro DII DD F12 F10 30 F9 F8 F7 F6 F4 & %3D 9 4. 5 6. Y * 00
- Draw structures 1 and 2. CI Zn(Hg) H 2 HCI 1. Compound 2 is an isomer of 1. 2. 'H-NMR 7.16 (m, 4H), 3.16 (1H), 2.84 (2H), 1.95 (2H), 1.26 (d, 3H). Create OscerSketch Answer 1 Provide the products of the first and second reaction. H3C Na/NH3/ELOH O3/(CH3)2S Create OscerSketch Answer 2In each reaction box, place the best reagent and conditions from the list. 1) CEN 2) 3) 4) 5) Answer Bank NANH, NaBH, acetone CH,CH, MgBr (excess) acetic acid acetate ion CH,OH, H,O* (cat.) LIAIH, (CH,),CHMgBr (excess) CH,MgBr (excess) H,0 H,0*, H,0, heat acetyl chlorideWhich of the following reactions will not produce a carboxylic acid? Benzaldehyde + hot, conc'd KMnO4 1) Ph-N2+ + KI 2) BrMgCH=CH2 in ether, followed by H3O+ sec-butylBenzene + hot, conc'd KMnO4 1) Benzene, HNO3 + H2SO4; 2) Fe, HCl; 3) NaNO2; 4) CuCN; 5) dilute acid and heat 1) Benzene and acetyl chloride & AlCl3; 2) HCl & Ni Thank you!