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- The acid-base indicator HIn undergoes the following reaction in dilute aqueous solution: HIncolor1H++Incolor2 The following absorbance data were obtained for a 5.00 I0-4 M solution of HIn in 0.1 M NaOH and 0.1 M HC1. Measurements were made at wavelengths of 485 nm and 625 nm with 1.00-cm cells. 0.1 M NaOH A485 = 0.075 A625 = 0.904 0.1 M HC1 A485 = 0.487 A625 = 0.181 In the NaOH solution, essentially all of the indicator is present as In-; in the acidic solution, it is essentially all in the form of HIn. (a) Calculate molar absorptivities for In- and HIn at 485 and 625 nm. (b) Calculate the acid dissociation constant for the indicator ¡fa pH 5.00 buffer containing a small amount of the indicator exhibits an absorbance of 0.567 at 485 nm and 0.395 at 625 nm (1.00-cm cells). (c) What is the pH of a solution containing a small amount of the indicator that exhibits an absorbance of0.492 at 485 nm and 0.245 at 635 nm (1.00-cm cells)? (d) A 25.00-mL aliquot of a solution of purified weak organic acid HX required exactly 24.20 mL of a standard solution of a strong base to reach a phenolphthalein end point. When exactly 12.10 mL of the base was added to a second 25.00-mL aliquot of the acid, which contained a small amount of the Indicator under consideration, the absorbance was found to be 0.333 at 485 nm and 0.655 at 625 nm (1.00-cmcells). Calculate the pH of the solution and Ka for the weak acid. (e) What would be the absorbance of a solution at 485 and 625 nm (1.50-cm cells) that was 2.00 10-4 M in the indicator and was buffered to a pH of 6.000?2. In one gravimetric analysis, the aluminum in a 1.2g sample of impure NHAI(SO4)2 was precipitate as hydrous ALO3.XH2O. The precipitate was filtered and ignited at 1000 °C to give anhydrous Al2O3 which weighed 0.1798g. Calculate the % Al inthe sample. 3. A sample of 0.4500g impure potassium chloride was dissolved in water treated with excess silver nitrate solution. 0.8402 g of silver chloride was precipitated. What is the percentage of potassium chloride in the sample?2.) A 0.2185g sample of NaCl was assayed using Volhard Method with 50mL 0f 0.0998N AgNO3 and 11.9mL of 0.1350N NH4SCN. Calculate the % NaCl in the sample.
- H1 gramof Sampleof an impure mixture af NARCOZ and Natteo, containing impurties is dissalved and tityated with SN Hel wit p colourless after addition5mD otacid-Methyt ge is then added and 22ontof, acid reguired orange tochange the of Naz coz benotphthalein as indicator, the sotudion Curns this indicator what is the percoulye and Na Heoz in the sample ?A sample of Al;(SO.); weighing 7.52-g was dissolved in enough water and diluted to 250.0-mL. 100.0-mL of the dilution was transferred to another flask, 10.0-mL of 0.050M EDTA, 20-ml of buffer solution, 50-mL of alcohol and 2.0-ml dithizone TS were added. The resulting solution required 8.7-mL of 0.031M ZnSO, to reach the endpoint. (Note: Each ml of 0.050M EDTA is equivalent to 16.66-mg Al:(SO.);•18H;0). Compute for the percent purity of the sample.A Sample Containfng mmol of KNOS is "parsed 6.00 x10-2² mmol of vesay ad z.00x102 mmol af ves@y ad 2.00x1o2 though a cation -excharye Column. the Colculate. volume o.02.00 M NaH of needed to titrete the elwate,
- A 0.501 g sample of sulfathiazole was assayed usingdiazotization with 0.1905M NaNO2 VS, using 18.7 mLof the titrant. Each mL of 0.1 M NaNO2 is equivalentto 25.53 mg of C9H9N3O2S2. What is the % purity?A 0.64 g sample containing KCl ( mw = 74.6 ) is dissolved in 50mL of water and titrated to the Ag2CrO4 end point, requiring 26.2 mL of 0.15 M AgNO3 .The %w/w KCl in the sample is ?One of the CHEM3341 student Ms. Fatima Al Wahaibi wanted to analyse phosphate ion concentration in Fertilizer industry wastewater sample collected from Rusayl Industrial Estate using spectrophotometer method. She mixed 200.00 mL of wastewater sample which contains only Na;PO, (unknown molarity) with 400.00 mL of 0.0200 M K,PO4 in a one liter beaker to make a Solution A. She then transferred 25.00 mL of Solution A to a 250.00 mL volumetric flask and added distilled water up to the calibration mark to make up Solution B. The Concentration of phosphate ions in Solution B is known to contain 3.00 x 103 mol/L from the spectrophotometric analysis at 460 nm using 1 cm cuvette. Calculate the concentration of phosphate ion in wastewater and how many phosphate ions are present in this wastewater.
- A 0.64 g sample containing KCI ( mw = 74.6 ) is dissolved in 50mL of water and titrated to the Ag2CrO4 end point, requiring 26.2 mL of 0.15 M AGNO3 * ? .The %w/w KCI in the sample isSolutions of cobalt (II) ions have a magenta color with a molar absorptivity constant (e) value at 511 nm of 5.87 M-1cm-1. A 0.500 mL sample is transferred from a 50.0 mL stock solution of Co(NO3)2 and diluted with water to a final volume of 7.50 mL. The dilution had an absorbance value at 511 nm in a standard cuvette (1.00 cm light path) of 0.382. Calculate the mass of Co(NO3)2 contained in the original 50.0 mL stock solution.In the development o f an analytical method for the quantitative analysis o f iron using Atomic Absorption spectrophotometry (AAS), a linear calibration curve for standards o f 0.00, 5.00, 10.00, 15.00 and 20.00 ppm was prepared. An iron ore sample with an expected iron content o f 40-60% w/w is to be analysed by this method. An approximately 0.5-g sample is taken, dissolved in a minimum amount o f concentrated HC1 and diluted to 1 L in a volumetric flask using distilled water. A 5.00-mL aliquot is removed with a pipette. With explanation, to what volume (10, 25, 50, 100, 250 500 or 1000 mL) should the 5.00 mL aliquot be diluted, to minimize the uncertainty in the analysis?