3. A solution is 0.5 M NH4OCl. a. Determine the major species in this solution. b. Identify the strongest acid and strongest base in the solution and write the equilibrium reaction between these two. c. Calculate the equilibrium constant for the reaction in (b) using the equilibrium constants from Table 14.2 and 14.3 in your textbook.

Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
Section: Chapter Questions
Problem 127SCQ
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3. A solution is 0.5 M NH4OCl.

a. Determine the major species in this solution.

b. Identify the strongest acid and strongest base in the solution and write the equilibrium reaction between these two.

c. Calculate the equilibrium constant for the reaction in (b) using the equilibrium constants from Table 14.2 and 14.3 in your textbook. Note that the reaction for the autodissociation of water may also be helpful here.

d. Calculate the equilibrium concentrations of NH4 + , NH3, HOCl, and OCl- .

e. Use the equilibrium constant(s) from (c) to calculate the pH of the solution.

f. This problem generally reads “Calculate the pH of a 0.5 M NH4OCl solution.” Recap in general terms the steps taken to solve this problem.

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