3+ less 2- more 1+ 1- 0 4+ 2+ When O is the central atom of Cl₂ O, the formal charge on the central O atom is 0 When C1 is the central atom of Cl₂ O, the formal charge on the central Cl atom is 1+ When N is the central atom of HCNO, the formal charge on the central N atom is 1+ When O is the central atom of HCNO, the formal charge on the central O atom is 2+ An O atom is more electronegative than N and less electronegative than Cl. Since structures that place positive formal charges on the more electronegative atoms are more stable, for both Cl₂ O and HCNO the structure observed has the less electronegative atom as the central atom.
Electronic Effects
The effect of electrons that are located in the chemical bonds within the atoms of the molecule is termed an electronic effect. The electronic effect is also explained as the effect through which the reactivity of the compound in one portion is controlled by the electron repulsion or attraction producing in another portion of the molecule.
Drawing Resonance Forms
In organic chemistry, resonance may be a mental exercise that illustrates the delocalization of electrons inside molecules within the valence bond theory of octet bonding. It entails creating several Lewis structures that, when combined, reflect the molecule's entire electronic structure. One Lewis diagram cannot explain the bonding (lone pair, double bond, octet) elaborately. A hybrid describes a combination of possible resonance structures that represents the entire delocalization of electrons within the molecule.
Using Molecular Structure To Predict Equilibrium
Equilibrium does not always imply an equal presence of reactants and products. This signifies that the reaction reaches a point when reactant and product quantities remain constant as the rate of forward and backward reaction is the same. Molecular structures of various compounds can help in predicting equilibrium.
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