16. Ignoring stereochemistry, what is the enthalpy difference of the second propagation step of 1,3,5- trimethylcyclohexane, chlorine, and light going to the major mono-chlorinated product? + Bond Disassociation Energies (kcal/mole) Selectivity Ratios C-H C-F C-CI C-Br X-X H-X 1º 2° 3° 1༠ 98 107 81 68 F 38 136 F 1 1.2 1.4 2° 95 106 80 68 CI 58 103 Cl 1 4 5 3° 91 106 79 65 Br 46 88 Br 1 80 1700 a. -8 b. -22 c. -30 d. -58 e. not a.-d.

16. Ignoring stereochemistry, what is the enthalpy difference of the second propagation step of 1,3,5- trimethylcyclohexane, chlorine, and light going to the major mono-chlorinated product? + Bond Disassociation Energies (kcal/mole) Selectivity Ratios C-H C-F C-CI C-Br X-X H-X 1º 2° 3° 1༠ 98 107 81 68 F 38 136 F 1 1.2 1.4 2° 95 106 80 68 CI 58 103 Cl 1 4 5 3° 91 106 79 65 Br 46 88 Br 1 80 1700 a. -8 b. -22 c. -30 d. -58 e. not a.-d.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter8: Haloalkanes, Halogenation, And Radical Reactions

Section: Chapter Questions

Problem 8.22P: Following is a balanced equation for the allylic bromination of propene. CH2==CHCH3 + Br2 h...

See similar textbooks

Similar questions

HELP
Draw the major elimination and substitution products formed in this reaction. Use a dash or wedge bond to indicate stereochemistry of substituents on asymmetric centers, where applicable. Ignore any inorganic byproducts. Br H₂O heat ✓
Alcohols can be converted to alkyl chlorides using SOCl2 with complete inversion of stereochemistry. Using curved arrows draw the stepwise mechanism for chlorination of an alcohol. Be sure to include lone pairs necessary to the mechanism steps and any non-zero formal charges.
Following is a balanced equation for the allylic bromination of propene. CH2==CHCH3 + Br2 h CH2==CHCH2Br + HBr (a) Calculate the heat of reaction, H 0, for this conversion. (b) Propose a pair of chain propagation steps and show that they add up to the observed stoichiometry. (c) Calculate the H 0 for each chain propagation step and show that they add up to the observed H 0 for the overall reaction.
Need help!
Draw a structural formula for the major product of the reaction shown. Br2 =CHCH2CH3 H20 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. aste ChemDoodle Previous Next Save and Exi tv MacBook Air DD 80 888 F11 F12 F9 F10 F7 F8 F5 F6 F3 F4 & ( ) #3 $ % %3D 3 4 6 7 8 9. { } P E Y U D G H J K F > .. .. R
Draw a structural formula for the major product of the reaction shown.
#11
Kelerences Keview topic Draw a structural formula for the major product of the reaction shown. Cl2 H20 CH;CH2CH;CH=CHz • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. 2reg 2reg M) ots 2reg pts 2req 1 pts 2req 1 pts 2reg ...1 pts ChemDoodle Previous Next> Save and Exit APR tv MacBook Air 80 DII DD F3 F4 FS F6 F7 F8 F10 F1 F12 #3 $ & + 3 4 6. 7 8 %3D dele E Y | { } P [ F G H. J K C V N M ? .. .. * C0 B
Draw a structural formula for the major product of the reaction shown. H3C Cl2 H3C H20 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. opy aste ChemDoodle
Draw the structural formula of the product of the reaction shown below. + H₂O AAVIL H₂SO4 • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. Sn [F Ⓡ ChemDoodle
Draw a structural formula for the major organic product of the reaction shown. If two major products are formed, draw both (structures only; no plus sign). Ignore stereochemistry. CH;CH2 CH2CH3 C=C HBr H H Marvin JS - Troubleshooting Marvin JS - Compatibility N S Marvin JS P CI ChemAxon Br TI +