Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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- At a particular temperature a 2.00 L flask at equilibrium contains 2.80 x 104 mol N2, 2.50 x 10-5 mol O2, and 2.00 x 10-2 mol N2O. The 2 N2(9) + Oz(9) = 2 N¿O(g) chemical reaction is: b. Calculate the equilibrium concentration of all the gases. c. Calculate the Keq.arrow_forwardWhich of the following statements is FALSE regarding reactions in dynamic equilibrium? O a. At equilibrium, the rates of reactant and product formation are equal. O b. If a chemical species is removed in the system, the system will favor the reaction that forms back the removed species. O C. At equilibrium, the concentrations of all species are equal. O d. In an equilibrium system with Keg > 1, the [products]eg is greater than the [reactantsleg.arrow_forward1. Sulfur trioxide decomposes spontaneously to form sulfur dioxide and oxygen gases according to the following balanced equation: 2SO, 2SO2 w + O2 Under certain conditions, the equilibrium constant for the reaction is 6.9 x 107. What concentration of oxygen can be expected when 0.400 mol of SO,, comes into equilibrium in a 2.00-L vessel? a. 360 b. Is this mixture at equilibrium? In a 1.00-L container is placed 0.10 mol ofO, 0.50 mol of SO, and 0.20 mol of SO, If not, predict in which direction the reaction will shift. An equilibrium mixture of the same three gases is combined with 0.10 mol of Ar reaction responds by producing more SO, The c. 3 Explain this new equilibrium shift. d. Describe how might a sulfur trioxide manufacturer try to minimize this decomposition reaction? Please choose a method different from part c.arrow_forward
- 1. Consider the following equilibrium at constant pressure: Nx + 3Hz0 2 NH30 A mixture of 4.0 mol of N2 and 12.0 mol of H2 was placed initially in a vessel of volume of 20.0 L, and heated to 565 K. When a system had reached equilibrium, it was found that 4.0 mol of NH was present. a. Calculate the concentration of each species at equilibrium. b. Calculate the equilibrium constant of this reaction at 565 K. c. When the volume of the vessel was increased and the system allowed to come to a new equilibrium at the same temperature, 9.0 molof H, was found to be present. Calculate the new volume.arrow_forwardAt 100 oC the equilibrium constant, Kc , for the reaction shown below is 2.16 x 10-10. Calculate the equilibrium concentration of the CO(g) knowing that the starting concentration of COCl2(g) is 0.200 M. COCl2(g) ⇌ CO(g) + Cl2(g) A. 1.47 x 10-5 M B. 1.31 x 10-5 M C. 3.29 x 10-5 M D. 6.57 x 10-6 Marrow_forward25. What is the CORRECT equilibrium constant expression of the given chemical reaction: 2 NO(g) + Cl2(g) 2 NOCI(g)? = PNOCIP PC Kp = PNo Pc Paoc Kp A. В. PNO2 PNOCI (PNO1 (PCb] C. Kp PNOC Poy D. Kp-arrow_forward
- Consider the following exothermic chemical reaction at equilibrium: N2(g) + 3H2(g) – 2NH3(g) + 92.94 kJ Identify the three changes that will shift the equilibrium to the right. Select one or more: O a. Decreasing the volume O b. Removing some NH, O c. Adding some NH3 O d. Increasing the volume O e. Adding some N2 O f. Removing some N2arrow_forwardOxygen and ozone are allowed to come to equilibrium in the exothermic reaction 203(g) =302(g) Which change will increase the numerical value of the equilibrium constant, K? Periodic Table and Datasheet Select one: O a. adding more O2(g) O b. adding a suitable catalyst O c. decreasing the temperature O d. increasing the volume of the containerarrow_forwardConsider the following exothermic reaction: 4 NH3 (g) + 5 O2 (g) ⇋⇋ 4 NO (g) + 6 H2O (l) How would the equilibrium shift if NH3 is added to the reaction mixture? Select one: a. The reaction would shift to the right. b. The reaction would shift to the left. c. The equilibrium would not be affected.arrow_forward
- 7. The reaction for lime (CaO) production from limestone (CaCO3) is as follows: CACO3(s) + heat 2 CaO(s) + CO2(g) Which of the following statements is incorrect? A. Decreasing the temperature moves the equilibrium to the left. B. Increasing the temperature produces more CaO at equilibrium. C. Increasing the pressure increases the CaO concentration at equilibrium. D. Removing CO2 shifts the equilibrium from left to right.arrow_forwardChoose the process that will not disturb the following equilibrium. Co(g) + H20(g) = CO2(g) + H2(g) A. Removing co O B. Increasing the temperature O C. Adding a catalyst D. Removing H2arrow_forwardConsider the endothermic reaction: 2 NH3(g) 3 H2(g) + N2(g). What effect does each of the following changes have on the direction of equilibrium? a. increase [NH3] d. increase temperature b. decrease [N2] c. increase [H2] e. decrease temperature f. increase pressurearrow_forward
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