1. When a solution containing 234 mg of butanol (FM 74.12) and 312 mg of hexanol (FM 102.17) in 10.0 mL was separated by gas chromatography, the relative peak areas were butanol:hexanol 1.00:1.45. Considering butanol to be the internal standard, find the response factor for hexanol. 2. When 1.06 mmol of 1-pentanol and 1.53 mmol of 1-hexanol were separated by gas chromatography, they gave relative peak areas of 922 and 1 570 units, respectively. When 0.57 mmol of pentanol was added to an unknown containing hexanol, the relative chromatographic peak areas were 843:816 (pentanol:hexanol). How much hexanol did the unknown contain?

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1.
When a solution containing 234 mg of butanol (FM 74.12) and 312 mg of hexanol
(FM 102.17) in 10.0 mL was separated by gas chromatography, the relative peak
areas were butanol:hexanol 1.00:1.45. Considering butanol to be the internal
standard, find the response factor for hexanol.
2. When 1.06 mmol of 1-pentanol and 1.53 mmol of 1-hexanol were separated by
gas chromatography, they gave relative peak areas of 922 and 1 570 units,
respectively. When 0.57 mmol of pentanol was added to an unknown containing
hexanol, the relative chromatographic peak areas were 843:816
(pentanol:hexanol). How much hexanol did the unknown contain?
Transcribed Image Text:1. When a solution containing 234 mg of butanol (FM 74.12) and 312 mg of hexanol (FM 102.17) in 10.0 mL was separated by gas chromatography, the relative peak areas were butanol:hexanol 1.00:1.45. Considering butanol to be the internal standard, find the response factor for hexanol. 2. When 1.06 mmol of 1-pentanol and 1.53 mmol of 1-hexanol were separated by gas chromatography, they gave relative peak areas of 922 and 1 570 units, respectively. When 0.57 mmol of pentanol was added to an unknown containing hexanol, the relative chromatographic peak areas were 843:816 (pentanol:hexanol). How much hexanol did the unknown contain?
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