1. Consider the following data obtained through an instrumental analysis: C/ mM Signal / mV 0.1 15.8 0.2 22.6 0.3 47.2 0.4 88.7 0.5 101.9 Replicate 1 Replicate 2 Replicate 3 56.5 61.0 48.7 Here, the 0.1, 0.2, etc. represent the standard concentrations and the replicate measurements were obtained on an unknown. (a) Calculate the 95 % confidence interval for the unknown concentration determined through this analysis. (b) Estimate the limits of detection and quantification for the method.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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1. Consider the following data obtained through an instrumental analysis:
C / mM
Signal / mV
0.1
15.8
0.2
22.6
0.3
47.2
0.4
88.7
0.5
101.9
56.5
Replicate 1
Replicate 2
Replicate 3
61.0
48.7
Here, the 0.1, 0.2, etc. represent the standard concentrations and the replicate measurements were
obtained on an unknown.
(a) Calculate the 95 % confidence interval for the unknown concentration determined through this
analysis.
(b) Estimate the limits of detection and quantification for the method.
Transcribed Image Text:1. Consider the following data obtained through an instrumental analysis: C / mM Signal / mV 0.1 15.8 0.2 22.6 0.3 47.2 0.4 88.7 0.5 101.9 56.5 Replicate 1 Replicate 2 Replicate 3 61.0 48.7 Here, the 0.1, 0.2, etc. represent the standard concentrations and the replicate measurements were obtained on an unknown. (a) Calculate the 95 % confidence interval for the unknown concentration determined through this analysis. (b) Estimate the limits of detection and quantification for the method.
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