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Science
Chemistry
1, Solve the Schrodinger Equation (SE) of particle in a well (PIW) using complex exponential function √(x) = Aeikx + Be-ikx
1, Solve the Schrodinger Equation (SE) of particle in a well (PIW) using complex exponential function √(x) = Aeikx + Be-ikx
BUY
Physical Chemistry
2nd Edition
ISBN:
9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher:
Wadsworth Cengage Learning,
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1 Gases And The Zeroth Law Of Thermodynamics
2 The First Law Of Thermodynamics
3 The Second And Third Laws Of Thermodynamics
4 Gibbs Energy And Chemical Potential
5 Introduction To Chemical Equilibrium
6 Equilibria In Single-component Systems
7 Equilibria In Multiple-component Systems
8 Electrochemistry And Ionic Solutions
9 Pre-quantum Mechanics
10 Introduction To Quantum Mechanics
11 Quantum Mechanics: Model Systems And The Hydrogen Atom
12 Atoms And Molecules
13 Introduction To Symmetry In Quantum Mechanics
14 Rotational And Vibrational Spectroscopy
15 Introduction To Electronic Spectroscopy And Structure
16 Introduction To Magnetic Spectroscopy
17 Statistical Thermodynamics: Introduction
18 More Statistical Thermodynamics
19 The Kinetic Theory Of Gases
20 Kinetics
21 The Solid State: Crystals
22 Surfaces
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Chapter Questions
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Problem 10.1E: State the postulates of quantum mechanics introduced throughout the chapter in your own words.
Problem 10.2E
Problem 10.3E: State whether the following functions are acceptable wavefunctions over the range given. If they are...
Problem 10.4E: State whether the following functions are acceptable wavefunctions over the range given. If they are...
Problem 10.5E
Problem 10.6E
Problem 10.7E: Evaluate the operations in parts a, b, and f in the previous problem.
Problem 10.8E: The following operators and functions are defined: A=x()B=sin()C=1()D=10()p=4x32x2q=0.5r=45xy2s=2x3...
Problem 10.9E
Problem 10.10E: Indicate which of these expressions yield eigenvalue equations, and if so indicate the eigenvalue. a...
Problem 10.11E: Indicate which of these expressions yield an eigenvalue equation, and if so indicate the eigenvalue....
Problem 10.12E: Why is multiplying a function by a constant considered an eigenvalue equation?
Problem 10.13E
Problem 10.14E: Using the original definition of the momentum operator and the classical form of kinetic energy,...
Problem 10.15E: Under what conditions would the operator described as multiplication by i the square root of 1 be...
Problem 10.16E: A particle on a ring has a wavefunction =12eim where equals 0 to 2 and m is a constant. Evaluate...
Problem 10.17E: Calculate the uncertainty in position, x, of a baseball having mass 250g moving at 160km/hr with an...
Problem 10.18E: For an atom of mercury, an electron in the 1s shell has a velocity of about 58(0.58) of the speed of...
Problem 10.19E: Classically, a hydrogen atom behaves as if it were 74pm across. What is the uncertainty in momentum,...
Problem 10.20E: The largest known atom, francium, has an atomic diameter of 540pm. What is the uncertainty in...
Problem 10.21E: How is the Bohr theory of the hydrogen atom inconsistent with the uncertainty principle? In fact, it...
Problem 10.22E: Though not strictly equivalent, there is a similar uncertainty relationship between the observables...
Problem 10.23E: The uncertainty principle is related to the order of the two operators operating on a wavefunction....
Problem 10.24E
Problem 10.25E
Problem 10.26E: For a particle in a state having the wavefunction =2asinxa in the range x=0toa, what is the...
Problem 10.27E
Problem 10.28E: A particle on a ring has a wavefunction =eim, where =0to2 and m is a constant. a Normalize the...
Problem 10.29E
Problem 10.30E
Problem 10.31E
Problem 10.32E: Normalize the following wavefunctions over the range indicated. You may have to use the integral...
Problem 10.33E
Problem 10.34E
Problem 10.35E: For an unbound or free particle having mass m in the complete absence of any potential energy that...
Problem 10.36E
Problem 10.37E
Problem 10.38E
Problem 10.39E: Evaluate the expression for the total energies for a particle having mass m and a wavefunction...
Problem 10.40E
Problem 10.41E: Verify that the following wavefunctions are indeed eigenfunctions of the Schrdinger equation, and...
Problem 10.42E: In exercise 10.41a, the wavefunction is not normalized. Normalize the wavefunction and verify that...
Problem 10.43E
Problem 10.44E
Problem 10.45E: Explain why n=0 is not allowed for a particle-in-a-box.
Problem 10.46E
Problem 10.47E
Problem 10.48E
Problem 10.49E: Carotenes are molecules with alternating CC and C=C bonds in which the electrons are delocalized...
Problem 10.50E: The electronic spectrum of the molecule butadiene, CH2=CHCH=CH2, can be approximated using the one...
Problem 10.51E
Problem 10.52E
Problem 10.53E: Show that the normalization constants for the general form of the wavefunction =sin(nx/a) are the...
Problem 10.54E
Problem 10.55E
Problem 10.56E: An official baseball has a mass of 145g. a Assuming that a baseball in New Orleans Superdome width...
Problem 10.57E: Is the uncertainty principle consistent with our description of the wavefunctions of the 1D...
Problem 10.58E
Problem 10.59E
Problem 10.60E: Instead of x=0 to a, assume that the limits on the 1-D box were x=+(a/2) to (a/2). Derive acceptable...
Problem 10.61E: In a plot of ||2, the maximum maxima in the plot is/are called the most probable positions. What...
Problem 10.62E
Problem 10.63E
Problem 10.64E: The average value of radius in a circular system, r, is determined by the expression r=0r4r2dr. a...
Problem 10.65E
Problem 10.66E
Problem 10.67E
Problem 10.68E
Problem 10.69E
Problem 10.70E: Assume that for a particle on a ring the operator for the angular momentum, p, is i(/). What is the...
Problem 10.71E: Mathematically, the uncertainty A in some observable A is given by A=A2A2. Use this formula to...
Problem 10.72E
Problem 10.73E
Problem 10.74E: Verify that the wavefunctions in equation 10.20 satisfy the three-dimensional Schrdinger equation.
Problem 10.75E: An electron is confined to a box of dimensions 2A3A5A. Determine the wavefunctions for the five...
Problem 10.76E: a What is the ratio of energy levels having the same quantum numbers in a box that is 1nm1nm1nm and...
Problem 10.77E: Consider a one-dimensional particle-in-a-box and a three-dimensional particle-in-a-box that have the...
Problem 10.78E
Problem 10.79E
Problem 10.80E
Problem 10.81E
Problem 10.82E: What are x,y, and z for 111 of a 3-D particle-in-a-box? The operators for y and z are similar to the...
Problem 10.83E
Problem 10.84E
Problem 10.85E
Problem 10.86E
Problem 10.87E
Problem 10.88E
Problem 10.89E: Substitute (x,t)=eiEt/(x) into the time-dependent Schrdinger equation and show that it does solve...
Problem 10.90E: Write (x,t)=eiEt/(x) in terms of sine and cosine, using Eulers theorem: ei=cos+isin. What would a...
Problem 10.91E
Problem 10.92E
Problem 10.93E
Problem 10.95E
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1, Solve the Schrodinger Equation (SE) of particle in a well (PIW) using complex exponential function √(x) = Aeikx + Be-ikx
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