(1) Calculate the heat capacity (Ccal) for the calorimeter done in the lab, part 4. All of the heat leaving the hot water will go into either into the cold water or the coffee cup calorimeter. Be cautious about the signs. The q for the hot water is negative (heat leaving the system) and the q for the cold value for your calorimeter. You will get the heat capacity by multiplying the specific heat of the substance by water and cup will be positive (heat entering the cold water and cup). The calorimeter constant is a fixed its mass. The specific heat (Cs) of water is 4.184 J/g C = -Qhot cold + acup Ccup = [masShot X CSwater X AT hot ]-[mass cold X CS water X AT cold] AT cold Solve for Ccup. Show your work below. It should be around 10-30 J/°C for your calorimeter.

(1) Calculate the heat capacity (Ccal) for the calorimeter done in the lab, part 4. All of the heat leaving the hot water will go into either into the cold water or the coffee cup calorimeter. Be cautious about the signs. The q for the hot water is negative (heat leaving the system) and the q for the cold value for your calorimeter. You will get the heat capacity by multiplying the specific heat of the substance by water and cup will be positive (heat entering the cold water and cup). The calorimeter constant is a fixed its mass. The specific heat (Cs) of water is 4.184 J/g C = -Qhot cold + acup Ccup = [masShot X CSwater X AT hot ]-[mass cold X CS water X AT cold] AT cold Solve for Ccup. Show your work below. It should be around 10-30 J/°C for your calorimeter.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter6: Thermochemistry

Section: Chapter Questions

Problem 112AE: In a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each...

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A 29.1-mL sample of 1.05 M KOH is mixed with 20.9 mL of 1.07 M HBr in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 21.8C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, and volumes are additive.
A 21.3-mL sample of 0.977 M NaOH is mixed with 29.5 mL of 0.918 M HCl in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 19.6C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, the specific heat of all solutions is the same as that of water, and volumes are additive.
A sample of sucrose, C12H22O11, is contaminated by sodium chloride. When the contaminated sample is burned in a bomb calorimeter, sodium chloride does not burn. What is the percentage of sucrose in the sample if a temperature increase of 1.67C is observed when 3.000 g of the sample are burned in the calorimeter? Sucrose gives off 5.64103kJ/mol when burned. The heat capacity of the calorimeter and water is 22.51 kJ/C.
9.104 An engineer is using sodium metal as a cooling agent in a design because it has useful thermal properties. Looting up the heat capacity, the engineer finds a value of 28.2 J mol-l °C-l. Carelessly, he wrote this number down without units. As a result, it was later taken as specific heat. (a) What would he the difference between these two values? (b) Would the engineer overestimate the ability of sodium to remove heat from the system or underestimate it because of this error? Be sure to explain your reasoning.
Assume 200. mL of 0.400 M HCl is mixed with 200. mL of 0.400 M NaOH in a coffee-cup calorimeter The temperature of the solutions before mixing was 25.10 C; after mixing and allowing the reaction to occur, the temperature is 27.78 C. What is the enthalpy change when one mole of acid is neutralized? (Assume that the densities of all solutions are 1.00 g/mL and their specific heat capacities are 4.20 J/g K.)
In a constant-volume calorimeter, 35.0g of H2cools from 75.3C to25.0C. Calculate w, q, U, and H for the process.
Use data from Table 4.2 to calculate the standard combustion enthalpy for conversion of sulfur dioxide, SO2(g), to sulfur trioxide, SO3(g). Table 4.2 Selected Standard Formation Enthalpies, fH, at 25C
A 50-mL solution of a dilute AgNO3 solution is added to 100 mL of a base solution in a coffee-cup calorimeter. As Ag2O(s) precipitates, the temperature of the solution increases from 23.78 C to 25.19 C. Assuming that the mixture has the same specific heat as water and a mass of 150 g, calculate the heat q. Is the precipitation reaction exothermic or endothermic?
Explain the difference between heat capacity and specific heat of a substance.
The combustion of 1.00 mol liquid methyl alcohol (CH3OH) in excess oxygen is exothermic, giving 727 kJ of heat. (a) Write the thermochemical equation for this reaction. (b) Calculate the enthalpy change that accompanies the burning 10.0 g methanol. (c) Compare this with the amount of heat produced by 10.0 g octane, C8H18, a component of gasoline (see Exercise 5.41).
A 0.470-g sample of magnesium reacts with 200 g dilute HCl in a coffee-cup calorimeter to form MgCl2(aq) and H2(g). The temperature increases by 10.9 C as the magnesium reacts. Assume that the mixture has the same specific heat as water and a mass of 200 g. (a) Calculate the enthalpy change for the reaction. Is the process exothermic or endothermic? (b) Write the chemical equation and evaluate H.

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