1-bromo-5-chloropentane LDA 1 eq a) Hg(OAc)2 b) NaBH NaOH (1 eq) CHOO Note this product has a ring. The nucleophile and the alkene in this reaction are both in the same molecule! Also remember that alcohols react much like water! CH10O Note this product has both alcohol and alkene functional groups Br Br CH₂ONa (1 eq) + S2 OCH
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- Give IUPAC names for the following structures. When appropriate, abbreviate ortho (o), meta (m), and para (p), no italics, if you elect to use these terms. CH₂CH₂CHCHCHSCHCH₂ I T CH₁ CH₂ 1st structure: CH3 CH3 I 2nd structure: Submit Submit Answer Try Another Version OCH3 CH₂CCH₂ OCH3 10 item attempts remainingR'R?CHOH-CR°R* R'R?C=CR®R* What should orientation of each substituent in reactant to convert it into product alkene? What is importance of their specific orientation?What is the organic product formed in the following reaction? C6H5-CH=CH-C-C6H5 ÷ (CH3CH2)2NH O C6H-CH-CH-C-C6H5 (CH3CH2)2N || III CH-CH, CH- (CH3CH2)2N -CH OH IV O-N(CH2CH3)2 C6H3-CH=CH-C-CH¸ CH-CH=CH-C-CHS (CH3CH₁₂N Select one: A. IV B. II OC. III D. I F1 10: - F2 80 F3 000 000 FA
- What is the predicted product formed when cyclohexanecarbaldehyde reacts with excess 2-propanol in the presence of sulfuric acid? 01 0 1 0 ||| OIV OV OH OH لیکن پہلی بیٹی || IVName the following compounds properly, including stereochemistry. CH3 H3C a) b) он Br e leom d Son lasal Br cle e en S) Draw the structures of the following compounds. a) acetonitrile Jud iyrdem snonet b) benzonitrile c) acetic acid d) formic acid outoge e) propyl propanoate y o trans Draw specific (no R's) examples of: the tet a) a hemiacetal b) a phosphorus ylide. c) an acid chloride d) a hydrate The reaction of acetone with NABH4 is a) a hydration b) a hydrolysis c) an oxidation d) a reduction pts) "Soap" may be defined as: a) a long chain carboxylic acid b) the sodium salt of a long chain acid c) the methyl ester of a long chain acid d) an anhydride of a long chain acid4. A student was asked to prepare an alkene X in high yield using any alcohol as starting material CH3 CH,-C -CH=CH, CH3 X He chose 3, 3-dimethylbutan-2-ol (XI) and carried out a dehydration reaction. He was however horrified to note that the only alkene obtained was XII. CH3 OH CH3 CH;-C=C-CH3 conc. H,SO4 CH-CH3 heat CH3 CH3 XI XII i) Explain what went wrong here, and why X could not be formed from 3, 3-dimethylbutan-2-ol. Use structures to help support your answer. ii) Give an equation to show a much better method for preparing X in high yield. 5. Analyze the following structure and write one combination for Grignard reagent and a carbonyl that would give rise to it. CH,-CH,-OH
- Draw a structural formula for the major organic product of the reaction shown below. & CH₂ (oran CH3CH₂O -CuLi 2 ether You do not have to consider stereochemistry. Sn [F ? ChemDoodle H3O +4. What are the products obtained from the following elimination reaction? Indicate the major product. CH;CH2CCH3 H2O CI 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH3 Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.1. Starting from 1-bromoethane, synthesize ethanenitrile Br CH;CEN 1-bromoethane ethanenitrile 2. Starting from ethyne, synthesize butanamide HC=CH ethyne *NH2 butanamide 3. Starting from ethanol, synthesize methylbutyrate `OH ethanol methyl butyrate
- Name the following organic compound: CH3 S CH CH3 CH 0 CH, CH, 3-methylsulfide-2-ethoxy butane 2-ethoxy-3-methylthio butane O 3-ethoxy-2-methylthio butane O 2-methylsulfide-3-ethoxy butane O 2-ethoxy-3-methylsulfide butaneDraw a structural formula for the product formed upon hydroboration/oxidation of the alkene below. CH3 OG 1 Use wedge and hash bonds ONLY for rings. Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. ● 981 CH3 ***** // Q Y ? [F BDraw a structural formula for the major product of the reaction shown. H3C Cl2 H3C H20 Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer. opy aste - [F ChemDoodle Previous Nex