. Of the two unimolecular reactions shown, decide which you think would be faster, i.e., which would have a higher relative rate constant (krel)? 2. Based on your answer, draw two lines on one reaction coordinate diagram that show the relative progress of each reaction along its path to product indicated? 3. what is Bond dissociation energy of the C-LG bond? 4. what is the Nature of the leaving group (LG)? 5. what is the relative size of activation energy (Ea) for each reaction? 6. what is the Hammond's postulate? 7. what are the Relative thermodynamic stability of the reactive intermediates? 8. what is Influence of the solvent (if given) on the reactions and intermediates?

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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1. Of the two unimolecular reactions shown, decide which you think would be faster, i.e., which would have a higher relative rate constant (krel)?

2. Based on your answer, draw two lines on one reaction coordinate diagram that show the relative progress of each reaction along its path to product indicated?

3. what is Bond dissociation energy of the C-LG bond?

4. what is the Nature of the leaving group (LG)?

5. what is the relative size of activation energy (Ea) for each reaction?

6. what is the Hammond's postulate?

7. what are the Relative thermodynamic stability of the reactive intermediates?

8. what is Influence of the solvent (if given) on the reactions and intermediates?

 

 

.CI
cP (1)
CI
(2)
Transcribed Image Text:.CI cP (1) CI (2)
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