Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 4.SE, Problem 60AP
Interpretation Introduction
Interpretation:
The relationship between two different substances shown and named as trans-1,2-dimethylcyclopentane is to be stated.
Concept introduction:
Compounds having a carbon attached to four different groups are optically active and exist as mirror image isomers called enantiomers.
To state:
The relationship between two different substances shown and named as trans-1,2-dimethylcyclopentane.
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Chapter 4 Solutions
Organic Chemistry
Ch. 4.1 - Give IUPAC names for the following cycloalkanes:Ch. 4.1 - Draw structures corresponding to the following...Ch. 4.1 - Name the following cycloalkane:Ch. 4.2 - Prob. 4PCh. 4.2 - Draw the structures of the following molecules:...Ch. 4.2 - Prostaglandin F2α, a hormone that causes uterine...Ch. 4.2 - Name the following substances, including the cis-...Ch. 4.3 - Each H↔H eclipsing interaction in ethane costs...Ch. 4.3 - cis-1, 2-Dimethylcyclopropane has more strain than...Ch. 4.4 - Prob. 10P
Ch. 4.4 - Two conformations of cis-l, 3-dimethylcyclobutane...Ch. 4.6 - Draw two different chair conformations of...Ch. 4.6 - Draw two differant chair conformations of trans-1,...Ch. 4.6 - Prob. 14PCh. 4.7 - What is the energy difference between the axial...Ch. 4.7 - Prob. 16PCh. 4.7 - Look at Figure 4-12 on page 105, and estimate the...Ch. 4.8 - Draw the more stable chair conformation of the...Ch. 4.8 - Identify each substituent in the following...Ch. 4.9 - Which isomer is more stable, cis-decalin or...Ch. 4.9 - Look at the following structure of the female...Ch. 4.SE - Prob. 22VCCh. 4.SE - Name the following compound, identify each...Ch. 4.SE - A trisubstituted cyclohexane with three...Ch. 4.SE - The following cyclohexane derivative has three...Ch. 4.SE - Prob. 26VCCh. 4.SE - Draw the five cycloalkanes with the formula C5H10.Ch. 4.SE - Draw two constitutional isomers of cis-1,...Ch. 4.SE - Prob. 29APCh. 4.SE - Tell whether the following pairs of compounds are...Ch. 4.SE - Prob. 31APCh. 4.SE - Prob. 32APCh. 4.SE - Draw 1, 3, 5-trimethylcyclohexane using a hexagon...Ch. 4.SE - Hydrocortisone, a naturally occurring hormone...Ch. 4.SE - A 1, 2-cis disubstituted cyclohexane, such as...Ch. 4.SE - A 1, 2-trans disubstituted cyclohexane must have...Ch. 4.SE - Prob. 37APCh. 4.SE - Which is more stable, a 1, 4-trans disubstituted...Ch. 4.SE - cis-1, 2-Dimethylcyclobutane is less stable than...Ch. 4.SE - From the data in Figure 4-12 and Table 4-1,...Ch. 4.SE - Prob. 41APCh. 4.SE - Draw the two chair conformations of...Ch. 4.SE - Draw the two chair conformations of...Ch. 4.SE - Galactose, a sugar related to glucose, contains a...Ch. 4.SE - There are four cis-trans isomers of menthol...Ch. 4.SE - There are four cis-trans isomers of menthol...Ch. 4.SE - The diaxial conformation of cis-1,...Ch. 4.SE - Approximately how much steric strain does the...Ch. 4.SE - In light of your answer to Problem 4-43, draw the...Ch. 4.SE - Prob. 50APCh. 4.SE - Prob. 51APCh. 4.SE - Using molecular models as well as structural...Ch. 4.SE - trans-Decalin is more stable than its cis isomer,...Ch. 4.SE - As mentioned in Problem 3-53, the statin drugs,...Ch. 4.SE - myo-Inositol, one of the isomers of...Ch. 4.SE - How many cis–trans stereoisomers of myo-inositol...Ch. 4.SE - The German chemist J. Bredt proposed in 1935 that...Ch. 4.SE - Tell whether each of the following substituents on...Ch. 4.SE - Prob. 59APCh. 4.SE - Prob. 60APCh. 4.SE - Ketones react with alcohols to yield products...Ch. 4.SE - Alcohols undergo an oxidation reaction to yield...
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- 9) There are 3 different cyclopropane molecules with the formula GHĄC12. a. Draw and build the 3 molecules. b. Below each drawing, name each molecule with correct nomenclature. Label a pair that are constitutional isomers. d. Label a pair that are stereoisomers (or configurational isomers). С.arrow_forward3. Which of the following compounds would you expect to have the greatest density: hexane,1-bromohexane, 1-fluorohexane, or 1-chlorohexane? Explain your answer.arrow_forwardCompound: 1-(isopropyl)-2-methylcyclohexane Sketch the line drawing of all the isomers of this compound (showing the 3D nature of the compound with wedges and dashes)arrow_forward
- Here is the chemical structure of 2-bromobutane: H H. H C-C-H H :Br: H H Decide whether each molecule in the table below is another molecule of 2-bromobutane, a molecule of an isomer of 2-bromobutane, or a molecule of an entirely different compound. molecule relationship to 2-bromobutane CH, (Choose one) H,c=ċ=CH,-Br Explanation Check O 2021 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Center I Accessibility P Type here to search 76°F DELL F1 F2 F3 F4 F5 FB F9 F10 F11 F12 PrtScr PAA @ %23 2$ 1 8. 9 Q W R Y. A F G H. K V N4 Alt Ctri Alt Σ B. C1arrow_forward1. Does chlorophyll a or chlorophyll b have a greater number of “conjugated” double bonds, or do they have the same number? Draw the structure of chlorophyll b and using a colored highlighter, indicate which of the double bonds are “conjugated”. 2. What is the main functional group in THF (tetrahydrofuran)? Is THF more polar or less polar than IPA (also called: isopropyl alcohol, isopropanol, or 2-propanol)? 3.If you mistakenly used hexanes-THF (2:1) for eluting the carotene pigments from your chromatography column, will they elute faster or slower than if you had correctly used hexanes-THF (10:1)? Explainarrow_forwardExtra credit 2. There are three different ways to draw dichloroethene (C2H2Cl2). Complete all three structures (isomers) by adding H and Cl atoms.arrow_forward
- Estimate the heat released when 1-butene(CH3CH2CHCH2) reacts with bromine to give CH3CH2CHBrCH2Br. Bond enthalpies are CH : 412 kJ/mol; CC : 348 kJ/mol;CC : 612 kJ/mol; CBr : 276 kJ/mol;BrBr : 193 kJ/mol. 1.317 kJ/mol 2.507 kJ/mol 3.95 kJ/mol 4.288 kJ/mol 5.181 kJ/molarrow_forwardFatty acids are molecules with a carboxylic acid on one end and long hydrocarbon chain on the other. The sodium salts of fatty acids (such as sodium strearate, shown below) are commonly used in soaps to trap nonpolar dirt and grease particles. Soap does not work well in "hard water, which is water with high concentration of magensium and calcium ions (often found in water obtained from wells) Explain this observation at a molecular level.arrow_forwardIt is easy to imagine a cyclohexane as a flat hexagon and a lot of the time we draw it that way. Looking at 1,3,5-triethylcyclohexane we cannot tell the stability of the molecule from looking at the flat 2D drawing. Explain why we need to look at the 3D configuration and what conformation (axial,equatorial) would each of the three ethyl groups be in for the most stable configuration.arrow_forward
- Replace one of the H atoms in the ethane model with a Br atom, to form ethyl bromide CH3CH2Br, and draw a projection (lewis) and a perspective drawing. Does replacing different hydrogen atoms in CH3CH3 to produce Ch3CH2br give you different isomers? (i.e. Are all the hydrogen atoms equivalent?) How many isomers of CH3CH2Br can you construct? Make a model of one other conformer of CH3CH2Br. DId you need to break any bonds to form the second conformer from the first?arrow_forward2. Draw all of the stereoisomers of dichlorocyclopentane. Use dashed lines and wedges (Hint: you should have 7 different/unique structures)arrow_forwardWhich is more stable, cis–1,4-dimethylcyclohexane or the trans isomer? Draw the structure of the more stable isomer. Your structure should clearly distinguish between all axial and equatorial positions.arrow_forward
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