Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 6, Problem 83P
Interpretation Introduction
Interpretation:
To explain which one is more efficient as an antifreeze.
Concept Introduction:
The concept of one of the colligative properties: depression in freezing point is used here. When a salt is mixed to a solvent such as water, the freezing point is depressed according to the colligative properties of the solution.
The mathematical expression is given as follows:
Where,
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Introduction To General, Organic, And Biochemistry
Ch. 6.5 - Problem 6-1 How would we prepare 250 mL of a 4.4%...Ch. 6.5 - Prob. 6.2QCCh. 6.5 - Problem 6-3 How would we prepare 2.0 L of a 1.06 M...Ch. 6.5 - Prob. 6.4QCCh. 6.5 - Problem 6-5 If a 0.300 M glucose solution is...Ch. 6.5 - Problem 6-6 A certain wine contains 0.010 M NaHSO3...Ch. 6.5 - Prob. 6.7QCCh. 6.5 - Problem 6-8 A concentrated solution of 15% w/v KOH...Ch. 6.5 - Problem 6-9 Sodium hydrogen sulfate, NaHSO4, which...Ch. 6.8 - Prob. 6.10QC
Ch. 6.8 - Prob. 6.11QCCh. 6.8 - Prob. 6.12QCCh. 6.8 - Problem 6-13 What is the osmolarity of a 3.3% w/v...Ch. 6.8 - Prob. 6.14QCCh. 6 - 6-15 Answer true or false. (a) A solute is the...Ch. 6 - 6-16 Answer true or false. (a) Solubility is a...Ch. 6 - 6-17 Vinegar is a homogeneous aqueous solution...Ch. 6 - 6-18 Suppose you prepare a solution by dissolving...Ch. 6 - 6-19 In each of the following, tell whether the...Ch. 6 - 6-20 Give a familiar example of solutions of each...Ch. 6 - 6-21 Are mixtures of gases true solutions or...Ch. 6 - 6-22 Answer true or false. (a) Water is a good...Ch. 6 - 6-23 We dissolved 0.32 g of aspartic acid in 115.0...Ch. 6 - Prob. 10PCh. 6 - 6-25 A small amount of solid is added to a...Ch. 6 - 6-26 On the basis of polarity and hydrogen...Ch. 6 - Prob. 13PCh. 6 - 6-28 Which pairs of liquids are likely to be...Ch. 6 - Prob. 15PCh. 6 - 6-30 Near a power plant, warm water is discharged...Ch. 6 - 6-31 If a bottle of beer is allowed to stand for...Ch. 6 - 6-32 Would you expect the solubility of ammonia...Ch. 6 - Prob. 19PCh. 6 - Prob. 20PCh. 6 - 6-35 Describe how we would prepare the following...Ch. 6 - Prob. 22PCh. 6 - 6-37 Calculate the w/v percentage of each of these...Ch. 6 - 6-38 Describe how we would prepare 250 mL of 0.10...Ch. 6 - 6-39 Assuming that the appropriate volumetric...Ch. 6 - 6-40 What is the molarity of each solution? (a) 47...Ch. 6 - 6-41 A teardrop with a volume of 0.5 mL contains...Ch. 6 - Prob. 28PCh. 6 - 6-43 The label on a sparkling cider says it...Ch. 6 - Prob. 30PCh. 6 - 6-45 The label on ajar of jam says it contains 13...Ch. 6 - 6-46 A particular toothpaste contains 0.17 g NaF...Ch. 6 - 6-47 A student has a bottle labeled 0.750% albumin...Ch. 6 - 6-48 How many grams of solute are present in each...Ch. 6 - 6-49 A student has a stock solution of 30.0% w/v...Ch. 6 - Prob. 36PCh. 6 - Prob. 37PCh. 6 - Prob. 38PCh. 6 - 6-53 Dioxin is considered to be poisonous in...Ch. 6 - 6-54 An industrial wastewater contains 3.60 ppb...Ch. 6 - 6-55 According to the label on a piece of cheese,...Ch. 6 - Prob. 42PCh. 6 - Prob. 43PCh. 6 - Prob. 44PCh. 6 - Prob. 45PCh. 6 - 6-60 Predict which of these covalent compounds is...Ch. 6 - On the basis of Tables 6.1 and 6.2 , classify the...Ch. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - 6-67 Calculate the freezing points of solutions...Ch. 6 - 6-68 If we add 175 g of ethylene glycol, C2H6O2,...Ch. 6 - Prob. 53PCh. 6 - 6-70 In winter, after a snowstorm, salt (NaCI) is...Ch. 6 - 6-71 A 4 M acetic acid (CH3COOH) solution lowers...Ch. 6 - Prob. 56PCh. 6 - 6-73 In each case, tell which side (if either)...Ch. 6 - 6-74 An osmotic semipermeable membrane that allows...Ch. 6 - 6-75 Calculate the osmolarity of each of the...Ch. 6 - Prob. 60PCh. 6 - Prob. 61PCh. 6 - Prob. 62PCh. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Prob. 65PCh. 6 - 6-78 (Chemical Connections 6A) Oxides of nitrogen...Ch. 6 - Prob. 67PCh. 6 - Prob. 68PCh. 6 - Prob. 69PCh. 6 - 6-82 (Chemical Connections 6C) A solution contains...Ch. 6 - 6-83 (Chemical Connections 6C) The concentration...Ch. 6 - 6-84 (Chemical Connections 6D) What is the...Ch. 6 - Prob. 73PCh. 6 - Prob. 74PCh. 6 - Prob. 75PCh. 6 - Prob. 76PCh. 6 - Prob. 77PCh. 6 - Prob. 78PCh. 6 - 6-91 When a cucumber is put into a saline solution...Ch. 6 - Prob. 80PCh. 6 - 6-93 Two bottles of water are carbonated, with CO2...Ch. 6 - Prob. 82PCh. 6 - Prob. 83PCh. 6 - 6-96 We know that a 0.89% saline (NaCI) solution...Ch. 6 - Prob. 85PCh. 6 - Prob. 86PCh. 6 - 6-99 A concentrated nitric acid solution contains...Ch. 6 - 6-100 Which will have greater osmotic pressure?...Ch. 6 - Prob. 89PCh. 6 - Prob. 90PCh. 6 - 6-103 A swimming pool containing 20,000. L of...Ch. 6 - Prob. 92PCh. 6 - Prob. 93PCh. 6 - Prob. 94PCh. 6 - Prob. 95PCh. 6 - Prob. 96PCh. 6 - Prob. 97PCh. 6 - Prob. 98PCh. 6 - 6-111 As noted in Section 6-8C, the amount of...Ch. 6 - 6-112 List the following aqueous solutions in...Ch. 6 - 6-113 List the following aqueous solutions in...Ch. 6 - Prob. 102P
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- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forward6-74 An osmotic semipermeable membrane that allows only water to pass separates two compartments, A and B. Compartment A contains 0.9% NaCI, and compartment B contains 3% glycerol C3H8O3. (a) In which compartment will the level of solution rise? (b) Which compartment (if either) has the higher osmotic pressure?arrow_forward6-113 List the following aqueous solutions in order of decreasing freezing point: 0.040 M glycerin (C3H8O3) 0.025 M NaBr, and 0.015 M AI(NO3)3 Assume complete dissociation of any salts.arrow_forward
- 6-67 Calculate the freezing points of solutions made by dissolving 1.00 mole of each of the following ionic solutes in 1000. g of H2O. (a) NaCI (b) MgCI2 (c) (NH4)2CO3 (d) AI(HCO3)3arrow_forward6-93 Two bottles of water are carbonated, with CO2 gas being added, under 2 atm pressure and then capped. One bottle is stored at room temperature; the other is stored in the refrigerator. When the bottle stored at room temperature is opened, large bubbles escape, along with a third of the water. The bottle stored in the refrigerator is opened without frothing or bubbles escaping. Explain.arrow_forward6-43 The label on a sparkling cider says it contains 22.0 g glucose (C6H12O6) 190. mg K+ , and 4.00 mg Na+ per serving of 240. mL of cider. Calculate the molarities of these ingredients in the sparkling cider.arrow_forward
- 6-32 Would you expect the solubility of ammonia gas in water at 2 atm pressure to be: (a) greater than, (b) the same as, or (c) smaller than at 0.5 atm pressure?arrow_forward6-53 Dioxin is considered to be poisonous in concentrations above 2 ppb. If a lake containing L has been contaminated by 0.1 g of dioxin, did the concentration reach a dangerous level?arrow_forwardThe freezing point of a 0.11 m solution of HNO2 is -0.20C. (a) What is i for the solution? (b) Is the solution made (i) of HNO2 molecules only? (ii) of H+ and NO2- only? (iii) of more HNO2 molecules than H+ ions? (iv) primarily of H+ and NO2- ions with some HNO2 molecules?arrow_forward
- The freezing point of a 0.21 m aqueous solution of H2SO4 is -0.796C. (a) What is i? (b) Is the solution made up primarily of (i) H2SO4 molecules only? (ii) H+ and HSO4- ions? (iii) 2H+ and 1SO42- ions?arrow_forwardSodium chloride (NaCl) is commonly used to melt ice on roads during the winter. Calcium chloride (CaCl2) is sometimes used for this purpose too. Let us compare the effectiveness of equal masses of these two compounds in lowering the freezing point of water, by calculating the freezing point depression of solutions containing 200. g of each salt in 1.00 kg of water. (An advantage of CaCl2 is that it acts more quickly because it is hygroscopic, that is. it absorbs moisture from the air to give a solution and begin the process. A disadvantage is that this compound is more costly.)arrow_forward6-103 A swimming pool containing 20,000. L of water is chlorinated to have a final CI2 concentration of 0.00500 M. What is the CI2 concentration in ppm? How many kilograms of CI2 were added to the swimming pool to reach this concentration?arrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY