Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 30, Problem 30.52P
(a) Explain why poly (vinyl alcohol) cannot be prepared by the radical 
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1.) Drawa) the constitutional formula of the compound ethylene oxide,andb) a section of the polymerization product of ethylene oxide "polyethylene glycol"!
2) Draw the conversion equation of formic acid and dimethylamine in aqueous solutionsolution and name the reaction product or products formed in the reaction
6. Dacron is the brand name for the polymer that is made from ethane-1,2-diol and benzene-1,4-dicarboxylic acid.
(a) When the two monomers combine, what type of reaction do they undergo and what molecule is
eliminated? [1] (b) What is the name for the linkages that join the monomers together? [1] (c) Draw the
monomers and the polymer of the reaction to create Dacron. [3]
What polymer is formed when CH2=CHCO2H (acrylic acid) is polymerized toform poly(acrylic acid)?
Chapter 30 Solutions
Organic Chemistry
Ch. 30 - Prob. 30.1PCh. 30 - Prob. 30.2PCh. 30 - Prob. 30.3PCh. 30 - Draw the mechanism for the radical polymerization...Ch. 30 - Prob. 30.5PCh. 30 - Prob. 30.6PCh. 30 - Prob. 30.7PCh. 30 - Prob. 30.8PCh. 30 - Prob. 30.9PCh. 30 - Prob. 30.10P
Ch. 30 - Prob. 30.11PCh. 30 - Problem 30.12
What polymer is formed by anionic...Ch. 30 - Prob. 30.13PCh. 30 - Prob. 30.14PCh. 30 - Problem 30.15
What polyamide is formed from each...Ch. 30 - Prob. 30.16PCh. 30 - Prob. 30.17PCh. 30 - Prob. 30.18PCh. 30 - Prob. 30.19PCh. 30 - Prob. 30.20PCh. 30 - Prob. 30.21PCh. 30 - Prob. 30.22PCh. 30 - Prob. 30.23PCh. 30 - Prob. 30.24PCh. 30 - Prob. 30.25PCh. 30 - 30.26 Draw the structure of the polymer formed by...Ch. 30 - Prob. 30.27PCh. 30 - Prob. 30.28PCh. 30 - Prob. 30.29PCh. 30 - 30.30 Draw each polymer in Problem 30.29 using the...Ch. 30 - Prob. 30.31PCh. 30 - Prob. 30.32PCh. 30 - Prob. 30.33PCh. 30 - Prob. 30.34PCh. 30 - Prob. 30.35PCh. 30 - Prob. 30.36PCh. 30 - Prob. 30.37PCh. 30 - Prob. 30.38PCh. 30 - 30.39 Draw a stepwise mechanism for the...Ch. 30 - 30.40 Cationic polymerization of 3-phenylpropene ...Ch. 30 - Prob. 30.41PCh. 30 - Prob. 30.42PCh. 30 - 30.43 Although styrene undergoes both cationic and...Ch. 30 - 30.44 Rank the following compounds in order of...Ch. 30 - Prob. 30.45PCh. 30 - Prob. 30.46PCh. 30 - 30.47 Draw a stepwise mechanism for the following...Ch. 30 - 30.48 Draw a stepwise mechanism for the reaction...Ch. 30 - 30.49 Draw the products of each reaction.
a. e....Ch. 30 - Prob. 30.50PCh. 30 - Prob. 30.51PCh. 30 - 30.52 (a) Explain why poly (vinyl alcohol) cannot...Ch. 30 - 30.53 Devise a synthesis of terephthalic acid and...Ch. 30 - Prob. 30.54PCh. 30 - Prob. 30.55PCh. 30 - 30.56 Compound A is a novel poly (ester amide)...Ch. 30 - 30.57 Researchers at Rutgers University have...Ch. 30 - 30.58 Melmac, a thermosetting polymer formed from...Ch. 30 - 30.59 Although chain branching in radical...Ch. 30 - Prob. 30.60P
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- Classify each of the following reactions as an addition, elimination, substitution, or rearrangement. (a) CH3B + KOH → CH3OH + KBr (b) CH3CH2Br — Н2С—СH2 + HBr (c) H2C=CH2 + H2 → CH3CH3arrow_forwardDraw the product resulting from mild oxidation of (a) 2-butanol; (b) 2-methylpropanal; (c) cyclopentanol.arrow_forwardDraw the organic product formed when the following compounds undergo a substitution reaction: (a) acetic acid and methylamine; (b) butanoic acid and 2-propanol; (c) formic acid and 2-methyl-1-propanol.arrow_forward
- (1) Write a complete chemical equation showing reactants, products, and catalysts needed (if any) for the following reaction and (2) Draw and name the organic compound found in every reaction. (a) Complete hydrogenation of 2-Methylhexa-1,5-diene (b) Complete halogenation (Br2) of 3-Ethyl-2,2-dimethylhept-3-ene (c) Reaction of (4E)-2.4-Dimethylhexa-1,4-diene with a mole of water (d) Reaction of cis-3,3-Dimethyl-4-propylocta-1,5-diene with two mole of HBr (e) Reaction of trans-1-Bromo-3-chlorocyclopentane with potassium hydroxide (f) Formation of Gilman reagent using isopropyl bromide (g) Ozonolysis of 3,3-Dimethyloct-4-yne (h) Complete halogenation (Cl2) of 3-Ethyl-5-methyl-1,6,8-decatriyne (i) Partial hydrogenation using Lindlar's Catalyst 2,2,5,5-Tetramethylhex-3-yne (i) Reaction of 3.4-Dimethylcyclodecyne with sodium amidearrow_forwardWhich products are formed when hydrobromic acid is added to (a) trans-2-hexene, (b) 2-methyl- 2-pentene, and (c) 4-methylcyclohexene, and how many regioisomers can be formed in each case?arrow_forwardStyrene derivatives such as A can be polymerized by way of cationic rather than radical intermediates. Cationic polymerization is an example of electrophilic addition to an alkene involving carbocations. a.) Draw a short segment of the polymer formed by the polymerization ofA.b.) Why does A react faster than styrene (C6H5CH=CH2) in a cationicpolymerization?arrow_forward
- Draw the organic product formed when the following com-pounds undergo a substitution reaction: (a) acetic acid and methylamine; (b) butanoic acid and 2-propanol; (c) formic acidand 2-methyl-1-propanol.arrow_forwardExplain the effects the addition of glycerol (a triol) will have on the molecular architecture of the following polymerization reactions: a) Condensation polymerization of terephthalic acid + ethylene glycol b) Condensation polymerization of 6-hydroxyhexanoic acidarrow_forwardEthers (general formula R—O—R)have many important uses. Until recently,methyl tert-butyl ether (MTBE, right)was used as an octane booster and fueladditive for gasoline. It increases the oxy-gen content of the fuel, which reducesCO emissions. MTBE is synthesized bythe catalyzed reaction of 2-methylpropene with methanol.(a) Write a balanced equation for the synthesis of MTBE. (Hint:Alcohols add to alkenes similarly to the way water does.)(b) If the government required that auto fuel mixtures contain2.7% oxygen by mass to reduce CO emissions, how many gramsof MTBE would have to be added to each 100. g of gasoline?(c) How many liters of MTBE would be in each liter of fuel mix-ture? (The density of both gasoline and MTBE is 0.740 g/mL.)(d) How many liters of air (21% O₂ by volume) are needed at24C and 1.00 atm to fully combust 1.00 L of MTBE?arrow_forward
- 1. which cannot be obtained by radical polymerization of its vinyl monomer Poly(ethylene) obtained by polymerization of ethylene monomer Poly(propylene) obtained by polymerization of propylene monomer Poly(vinyl chloride) obtained by polymerization of vinyl chloride monomer Poly(acrylonitrile) obtained by polymerization of acrylonitrile monomerarrow_forward4. Write the formula and name for the product when cyclopentene reacts with (a) Cl2(b) HBr(c) H2, Pt (d) H2O, H+arrow_forwardClassify each of the following reactions as an addition, elimination, substitution, or rearrangement: (a) CH3Br + KOH → CH3OH + KBr(b) CH3CH2Br → H2C=CH2 + HBr(c) H2C=CH2 + H2 → CH3CH3arrow_forward
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