a) Br 2 (1 equivalent) Interpretation: To draw the structure of the organic products from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Question

(a) Write the structures of main products when aniline reacts with the following reagents :(i) Br2 water (ii) HCI (iii) (CH3CO)2O/pyridine(b) Arrange the following in the increasing order of their boiling point :C2H5NH2, C2H5OH, (CH3)3N(c) Give a simple chemical test to distinguish between the following pair of compounds : (CH3)2NH and (CH3)3N

Answer 1

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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(a) Write the structures of main products when aniline reacts with the following reagents :(i) Br2 water (ii) HCI (iii) (CH3CO)2O/pyridine(b) Arrange the following in the increasing order of their boiling point :C2H5NH2, C2H5OH, (CH3)3N(c) Give a simple chemical test to distinguish between the following pair of compounds : (CH3)2NH and (CH3)3N

Give the structures of the substitution products expected when 1-bromohexane reacts with(a) NaOCH2CH3 (b) KCN (c) NaOH

n-Pentanol (CH3CH2CH2CH2CH2OH) and 2-methylbutan-2-ol (CH3CH2C(CH3)2OH) are converted to their corresponding alkyl chorides on being reacted with hydrogen chloride. (a) Write out an equation for each reaction (b) Assign each the appropriate symbol (SN1 or SN2) (c) Write a suitable mechanism for each reaction

Answer 2

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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Answer 3

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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Answer 4

Question

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

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Answer 5

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 6

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 7

Chapter 24.SE, Problem 60AP

Interpretation Introduction

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 8

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 9

Interpretation Introduction

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 10

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 11

Interpretation Introduction

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Answer 12

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Answer 13

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Answer 23

Ch. 24.1 - Name the following compounds:Ch. 24.1 - Prob. 2P Ch. 24.1 - Prob. 3P Ch. 24.3 - Prob. 4P Ch. 24.3 - The benzylammonium ion (C6H5CH2NH3+) has pKa =...Ch. 24.4 - Prob. 6P Ch. 24.5 - Prob. 7P Ch. 24.6 - Prob. 8P Ch. 24.6 - Prob. 9P Ch. 24.6 - Show two methods for the synthesis of dopamine, a...

a) Br 2 (1 equivalent) Interpretation: To draw the structure of the organic products from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Solution Summary: The author explains the structure of the compound from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Concept explainers

a) Br₂ (1 equivalent)

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

b) CH_{3_{I (excess)}}

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

c) CH₃COCl in pyridine

Interpretation:

To draw the structure of the organic products from the reaction of m-toulidine toluidine (m-methylaniline) with the following reagents.

Chapter 24 Solutions

a) Br 2 (1 equivalent) Interpretation: To draw the structure of the organic products from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Solution Summary: The author explains the structure of the compound from the reaction of m -toulidine toluidine (m-methylaniline) with the following reagents.

Concept explainers