Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 22, Problem 20QAP
Interpretation Introduction
(a)
Interpretation:
The structure of a compound having an alcohol of three carbon atoms possessing an -OH group on the centre of the chain should be drawn.
Concept introduction:
In structural formula, the bonding and type of bonds which holds the atoms in molecule together are shown.
Interpretation Introduction
(b)
Interpretation:
The structure of a compound having a
Concept introduction:
In structural formula, the bonding and type of bonds which holds the atoms in molecule together are shown.
Interpretation Introduction
(c)
Interpretation:
The structural of ester formed by the reaction between propan-2-ol and 2-methylpropanoic acid should be drawn.
Concept introduction:
In structural formula, the bonding and type of bonds which holds the atoms in molecule together are shown.
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. (a) The insecticide methoprene (see Fig. 7.32d) is an ester. Write the structural formulas for the alcohol and the carboxylic acid that react to form it. Name the alcohol.(b) Suppose that the carboxylic acid from part (a) is changed chemically so that the OCH3 group is replaced by a hydrogen atom and the COOH group is replaced by a CH3 group. Name the hydrocarbon that would result.
Draw complete structural diagrams of the
following compounds.
(a) 2-methyl,pent-2-ene
(b) propyne
(c) 2,3-dimethyl butane
(d) cycloheptane
The functional group of butanone is:(a) Carboxyl(b) ketonic(c) aldehydic(d) alcoholic
Chapter 22 Solutions
Chemistry: Principles and Reactions
Ch. 22 - Classify each of the following hydrocarbons as...Ch. 22 - Classify each of the following hydrocarbons as...Ch. 22 - Write the formula for (a) an alkene with two...Ch. 22 - Write the formula for (a) an alkyne with 16...Ch. 22 - Name the following alkanes.Ch. 22 - Name the following alkanes.Ch. 22 - Prob. 7QAPCh. 22 - Prob. 8QAPCh. 22 - The following names are incorrect; draw a...Ch. 22 - Prob. 10QAP
Ch. 22 - Prob. 11QAPCh. 22 - Prob. 12QAPCh. 22 - Prob. 13QAPCh. 22 - Name the following compounds as derivatives of...Ch. 22 - Prob. 15QAPCh. 22 - Prob. 16QAPCh. 22 - Prob. 17QAPCh. 22 - Prob. 18QAPCh. 22 - Prob. 19QAPCh. 22 - Prob. 20QAPCh. 22 - Prob. 21QAPCh. 22 - Prob. 22QAPCh. 22 - Prob. 23QAPCh. 22 - Arrange these compounds in order of increasing...Ch. 22 - The Kbfor ethylamine (CH3CH2NH2) is 4.3104 . What...Ch. 22 - When aniline, C6H5NH2(Kb=7.41010) , reacts with a...Ch. 22 - When ethylamine, a weak base (Kb=4.3104) , reacts...Ch. 22 - When the conjugate acid of aniline, C6H5NH3+,...Ch. 22 - Draw the structural isomers of the alkane C6H14.Ch. 22 - Prob. 30QAPCh. 22 - Prob. 31QAPCh. 22 - Draw the structural isomers of C3H6Cl2 in which...Ch. 22 - Prob. 33QAPCh. 22 - Prob. 34QAPCh. 22 - Prob. 35QAPCh. 22 - Prob. 36QAPCh. 22 - Draw structures for all the alcohols with...Ch. 22 - Prob. 38QAPCh. 22 - Prob. 39QAPCh. 22 - Prob. 40QAPCh. 22 - Maleic acid and fumaric acid are the cis- and...Ch. 22 - Prob. 42QAPCh. 22 - Which of the following can show optical isomerism?...Ch. 22 - Prob. 44QAPCh. 22 - Prob. 45QAPCh. 22 - Prob. 46QAPCh. 22 - Prob. 47QAPCh. 22 - Prob. 48QAPCh. 22 - Prob. 49QAPCh. 22 - Prob. 50QAPCh. 22 - Prob. 51QAPCh. 22 - Prob. 52QAPCh. 22 - Calculate [H+] and the pH of a 0.10 M solution of...Ch. 22 - Prob. 54QAPCh. 22 - The general formula of an alkane is CnH2n+2 . What...Ch. 22 - Prob. 56QAPCh. 22 - Prob. 57QAPCh. 22 - Prob. 58QAPCh. 22 - Prob. 59QAPCh. 22 - Write an equation for the reaction of chloroacetic...
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- Butanone is a four carbon compound with the functional group:(a) carboxylic acid(b) aldehyde(c) ketone(d) alcoholarrow_forward(a) Give the empirical formula and structural formula fora cyclic ether containing four carbon atoms in the ring.(b) Write the structural formula for a straight-chain compoundthat is a structural isomer of your answer to part (a).arrow_forwardIndicate whether each statement is true or false. (a) Pentanehas a higher molar mass than hexane. (b) The longer the linearalkyl chain for straight-chain hydrocarbons, the higherthe boiling point. (c) The local geometry around the alkynegroup is linear. (d) Propane has two structural isomers.arrow_forward
- (B) Draw a structural diagram for each of the following organic compounds: (a) 2-ethyl-4-methyl-2-pentanol (b) 1,2-ethandiol (c) 1,3-dimethylbenzenearrow_forwardAlcohols can be produced by the hydration of:(a) Alkenes(b) alkynes(c) alkanes(d) acidsarrow_forwardGive the structural formulae and name the functional groups of the following compounds. (a) 3-chlorobut-1-ene Name the functional group: (b) butanedioic acid Name the functional group: (c) propanamide Name the functional group: (d) 3-methylbutanal Name the functional group:arrow_forward
- TRUE OR FALSE (a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions. (b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom. (c) A primary alcohol has one —OH group, a secondary alcohol has two —OH groups, and a tertiary alcohol has three —OH groups. (d) There are two alcohols with the molecular formula C3H8O. (e) There are three amines with the molecular formula C3H9N. (f) Aldehydes, ketones, carboxylic acids, and esters all contain a carbonyl group. (g) A compound with the molecular formula of C3H6O may be either an aldehyde, a ketone, or a carboxylic acid. (h) Bond angles about the carbonyl carbon of an aldehyde, a ketone, a carboxylic acid, and an ester are all approximately 109.5°. (i) The molecular formula of the smallest aldehyde is C3H6O, and that of the smallest ketone is also C3H6O. (j) The molecular formula of the smallest carboxylic…arrow_forwardDraw the condensed structure of the compounds formedby condensation reactions between (a) benzoic acid andethanol, (b) ethanoic acid and methylamine, (c) acetic acidand phenol. Name the compound in each case.arrow_forwardPolychlorinated Biphenyls (PCBs) are chemicals formed by attaching one or more chlorine atoms to a pair of connected benzene rings. (a) Summarise the adverse health effects associated with exposure to PCBs. (b) With a suitable illustration, explain the action of PCBs toxicity.arrow_forward
- 5.Write the structural formula of the ester that, when hydrolyzed, would yield the following:(a) methanol and propanoic acid(b) 1-octanol and acetic acid (c) ethanol and butanoic acidarrow_forwardWrite a condensed structural formula for each of the following:(a) an acid with the formula C4H8O2, (b) a cyclicketone with the formula C5H8O, (c) a dihydroxy compoundwith the formula C3H8O2, (d) a cyclic ester with theformula C5H8O2.arrow_forwardDraw structures for the following compounds. Show all of the hydrogen atoms in the molecules. (a) ethanol (b) 2-propanol (c) 2-ethyl-5-methylcyclohexanolarrow_forward
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