General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 18, Problem 18.110CHP
A boiler with water that contained high concentrations of Ca2+ and SO42– —but no CO32–or HCO3– —developed a boiler scale. Elemental analysis of the scale showed 2.34% H and 55.76% O. Assuming the ions in the boiler scale are Ca2+ and SO42– and that the scale is a hydrate, what is its formula?
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b. (i)
(ii)
A green solid has the empirical formula FeBr3·5NH3 H₂O. Upon reaction with
an excess of aqueous AgNO3 it is found that 1 mole of the solid precipitates 3
moles of AgBr. Heating the green solid leads to loss of 1 mole of H₂O to yield
a blue solid with the same ratio of Fe:Br:NH3 as found in the green solid.
The reaction of 1 mole of the blue solid with excess of aqueous AgNO3
produces 2 moles of AgBr. Draw and name the octahedral green and blue
complexes.
An octahedral complex having the formula [M(dien)(NH3)(OH₂)F] has a total
of 15 isomers. In the sum formula "dien" represents the tridentate
diethylenetriamine ligand, which can adopt meridional or facial coordination
modes. Draw structures of 8 possible isomers, clearly showing any pairs of
enantiomers. The tridentante ligand may be abbreviated as below for
simplicity.
H₂N :
=
ΝΗ
NH :NH2 N
diethylenetriamine (dien)
N
N
Chapter 18 Solutions
General Chemistry: Atoms First
Ch. 18.1 - Prob. 18.1PCh. 18.1 - Prob. 18.2PCh. 18.2 - Prob. 18.3PCh. 18.3 - Write the chemical formula of a compound that...Ch. 18.4 - Prob. 18.5PCh. 18.4 - Prob. 18.6CPCh. 18.4 - Prob. 18.7PCh. 18.8 - Prob. 18.8CPCh. 18.8 - Prob. 18.9PCh. 18.9 - Prob. 18.10P
Ch. 18.9 - Prob. 18.11PCh. 18.9 - Prob. 18.12CPCh. 18.10 - Prob. 18.13PCh. 18.10 - Prob. 18.14PCh. 18.13 - Prob. 18.15PCh. 18.13 - Prob. 18.16PCh. 18.13 - Prob. 18.17PCh. 18 - Prob. 18.18CPCh. 18 - Look at the location of elements A, B, C, and D in...Ch. 18 - Prob. 18.20CPCh. 18 - Prob. 18.21CPCh. 18 - Prob. 18.22CPCh. 18 - Prob. 18.23CPCh. 18 - Prob. 18.24CPCh. 18 - Prob. 18.25CPCh. 18 - Prob. 18.26CPCh. 18 - Prob. 18.27CPCh. 18 - Prob. 18.28SPCh. 18 - Prob. 18.29SPCh. 18 - Prob. 18.30SPCh. 18 - Prob. 18.31SPCh. 18 - Prob. 18.32SPCh. 18 - Prob. 18.33SPCh. 18 - Prob. 18.34SPCh. 18 - Prob. 18.35SPCh. 18 - Prob. 18.36SPCh. 18 - Prob. 18.37SPCh. 18 - Prob. 18.38SPCh. 18 - Prob. 18.39SPCh. 18 - Prob. 18.40SPCh. 18 - Prob. 18.41SPCh. 18 - Prob. 18.42SPCh. 18 - Prob. 18.43SPCh. 18 - Prob. 18.44SPCh. 18 - Prob. 18.45SPCh. 18 - Prob. 18.46SPCh. 18 - Prob. 18.47SPCh. 18 - Prob. 18.48SPCh. 18 - Prob. 18.49SPCh. 18 - Prob. 18.50SPCh. 18 - Prob. 18.51SPCh. 18 - Prob. 18.52SPCh. 18 - Prob. 18.53SPCh. 18 - Prob. 18.54SPCh. 18 - Prob. 18.55SPCh. 18 - Prob. 18.56SPCh. 18 - Prob. 18.57SPCh. 18 - Prob. 18.58SPCh. 18 - Prob. 18.59SPCh. 18 - Prob. 18.60SPCh. 18 - Prob. 18.61SPCh. 18 - Prob. 18.62SPCh. 18 - Prob. 18.63SPCh. 18 - Prob. 18.64SPCh. 18 - Prob. 18.65SPCh. 18 - Which is more acidic? (a) Cr2O3 or CrO3 (b) N2O5...Ch. 18 - Prob. 18.67SPCh. 18 - Prob. 18.68SPCh. 18 - Write a balanced net ionic equation for the...Ch. 18 - Prob. 18.70SPCh. 18 - Prob. 18.71SPCh. 18 - Prob. 18.72SPCh. 18 - Prob. 18.73SPCh. 18 - What products are formed when the following metals...Ch. 18 - Prob. 18.75SPCh. 18 - Draw MO energy-level diagrams for O2, O2, and O22,...Ch. 18 - Prob. 18.77SPCh. 18 - Prob. 18.78SPCh. 18 - Prob. 18.79SPCh. 18 - Prob. 18.80SPCh. 18 - Prob. 18.81SPCh. 18 - Prob. 18.82SPCh. 18 - Prob. 18.83SPCh. 18 - Prob. 18.84SPCh. 18 - Prob. 18.85SPCh. 18 - Why does boiler scale form when hard water is...Ch. 18 - Prob. 18.87SPCh. 18 - Prob. 18.88SPCh. 18 - Prob. 18.89SPCh. 18 - Prob. 18.90SPCh. 18 - Prob. 18.91SPCh. 18 - Prob. 18.92SPCh. 18 - Prob. 18.93SPCh. 18 - Prob. 18.94CHPCh. 18 - Prob. 18.95CHPCh. 18 - Prob. 18.96CHPCh. 18 - Prob. 18.97CHPCh. 18 - Prob. 18.98CHPCh. 18 - Prob. 18.99CHPCh. 18 - Prob. 18.100CHPCh. 18 - Prob. 18.101CHPCh. 18 - Prob. 18.102CHPCh. 18 - Prob. 18.103CHPCh. 18 - Use the standard heats of formation in Appendix B...Ch. 18 - Prob. 18.105CHPCh. 18 - Prob. 18.106CHPCh. 18 - Prob. 18.107CHPCh. 18 - Prob. 18.108CHPCh. 18 - Prob. 18.109CHPCh. 18 - A boiler with water that contained high...Ch. 18 - Prob. 18.111CHPCh. 18 - Prob. 18.112CHPCh. 18 - Prob. 18.113CHPCh. 18 - Prob. 18.114CHPCh. 18 - Prob. 18.116MPCh. 18 - Prob. 18.117MPCh. 18 - Prob. 18.118MPCh. 18 - Prob. 18.120MPCh. 18 - Prob. 18.121MPCh. 18 - Prob. 18.122MPCh. 18 - Prob. 18.123MP
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