Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 15, Problem 15.25SP

(a)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(b)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(c)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(d)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(e)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(f)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(g)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(h)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

(i)

Interpretation Introduction

To determine: The product of the given reaction.

Interpretation: The product of the given reaction is to be predicted.

Concept introduction: The synthesis of compound relies upon the type of reactants and reagents that used during the reactions. The Stability of a product is the major factor that is responsible for the high yield of the product. The reagents perform many functions in reactions like proton abstraction, oxidation, reduction, catalysis, and dehydrogenation.

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Reagents a. CeHsCHO b. NaOH, ethanol c. Pyrrolidine, cat. H* j. Brz, H* d. H2C=CHCN e. H3O* f. h. BRCH2CH=CH2 i. Na* OEt, ethanol k. K* t-Buo I. CH2(CO,Et)2 m. heat CH2CH2CN LDA g. ELOC(=0)COEt Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
Reagents Available g. CO, HCI, CUCI/AICI3 h. CH3CH2CH2COCI, AICI3 i. BrCH2CH2Br, Он j. CH3CH2CI, AICI3 k. RCO3H I. H3O* a. CH2=CHCH,CI, AICI3 b. CH2B12, OH c. CH3CH2COCI, AICI3 d. H2, Pt e. NBS, CCI4 f. K* tBuO Using conditions from the table, show how you would synthesize this compound from catechol (1,2-benzenediol). Select reagents from the table in the order that you wish to use them, i.e. aced; do not include punctuation or spaces If more than one route exists, choose the shorter one; in no case will a synthesis require more than 5 steps.
Reagents a. HBr m. 2 equivalents of NaNH2 b. HBr, H2O2, hv c. H20, H2SO4 d. Br2 H2, Lindlar's catalyst Na / NH3 H2SO4, H9SO4 (sia)2BH then H2O2, NaOH n. O. 5 р. е. Cl q. 1 equivalent of NANH2 H2, Pd g. Br2, H2O h. Cl2, H2O OsO4 then NaHSO3 j. Hg(OAc)2, H2O then NABH4 k. BH3 then H2O2, NaOH Og then (CH3)2S f. r. S. NBS, hv Br2, hv Cl2, hv t. i. u. V. HCI I. 2 Previous Next

Chapter 15 Solutions

Organic Chemistry (9th Edition)

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