Concept explainers
(a)
Interpretation:
The product of the given reaction is to be predicted.
Concept introduction:
Steps for writing a correct mechanism are shown below.
- The atoms that contain double bond or those containing cations act as electrophiles.
- The atoms with lone pair act as nucleophiles.
- Identify the electrophiles site in the given compound.
- Draw the arrow starting from the correct site and ending at the correct site.
(b)
Interpretation:
The product of the given reaction is to be predicted.
Concept introduction:
Steps for writing a correct mechanism are shown below.
- The atoms that contain double bond or those containing cations act as electrophiles.
- The atoms with lone pair act as nucleophiles.
- Identify the electrophiles site in the given compound.
- Draw the arrow starting from the correct site and ending at the correct site.
(c)
Interpretation:
The product of the given reaction is to be predicted.
Concept introduction:
Steps for writing a correct mechanism are shown below.
- The atoms that contain double bond or those containing cations act as electrophiles.
- The atoms with lone pair act as nucleophiles.
- Identify the electrophiles site in the given compound.
- Draw the arrow starting from the correct site and ending at the correct site.
(d)
Interpretation:
The product of the given reaction is to be predicted.
Concept introduction:
Steps for writing a correct mechanism are shown below.
- The atoms that contain double bond or those containing cations act as electrophiles.
- The atoms with lone pair act as nucleophiles.
- Identify the electrophiles site in the given compound.
- Draw the arrow starting from the correct site and ending at the correct site.
(e)
Interpretation:
The product of the given reaction is to be predicted.
Concept introduction:
Steps for writing a correct mechanism are shown below.
- The atoms that contain double bond or those containing cations act as electrophiles.
- The atoms with lone pair act as nucleophiles.
- Identify the electrophiles site in the given compound.
- Draw the arrow starting from the correct site and ending at the correct site.
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Check out a sample textbook solutionChapter 14 Solutions
Organic Chemistry (9th Edition)
- Draw the products of the following reactions. If the products can exist as stereoisomers, show which stereoisomers are formed. a. cis-2-pentene + HCl b. trans-2-pentene + HCl c. 1-ethylcyclohexene + H2O + H2SO4 d. 2,3-dimethyl-3-hexene + H2, Pd/C e. 1,2-dimethylcyclohexene + HCl f. 1,2-dideuteriocyclohexene + H2, Pd/C g. 3,3-dimethyl-1-pentene + Br2/CH2Cl2 h. (E)-3,4@dimethyl-3-heptene + H2, Pd/C i. (Z)-3,4-dimethyl-3-heptene + H2, Pd/C j. 1-chloro-2-ethylcyclohexene + H2 , Pd/Carrow_forwardselect reagents: cyclopentanone Reagents a. C6H5CHO b. NaOH, ethanol c. Pyrrolidine, cat. Hj. d. H₂C=CHCN e. H3O+ f. LDA g. A) bg EtOC(=O)CO₂Et h. i. B) ka k. I. m. O: BrCH₂CH=CH₂ NatOEt, ethanol Br₂, H+ K+ t-BUO™ CH2(CO2Et)z heat C) jh CO₂Et D) Imarrow_forwardFrom the table of reagents shown below, show how you synthesize the product from the given reactant. Br Reagents available a. NBS, (PhCO2)2 h. CH3 Cl, AIC13 CUCN 0. b. Br2, FeBr3 i. CH3 CH2 Br р. НзО*, д с. Вг2, Н+ j. CH3O¯, A q. CH; CH2 COCI, AICI3 r. k. CH3 COCI, AICI3 H2NNH2, OH, A d. OH- e. NaOH(s), A 1. Mg, Et20 s. H2, Pd/C f. HNO3, H,SO4 m. CO2(s) then H3O+ t. H3PO2 g. H2 CrO4 n. HONO 0°C u. Cl2, FeCl3 (Enter the letter(s) of the reagent(s) needed in the box, in the order that they must be used. No more than two steps are required to perform the synthesis. Note that a retrosynthetic arrow is used, and therefore the reactant is shown on the right.) Answer:arrow_forward
- From the table of reagents shown below, show how you synthesize the product from the given reactant. H3C NO₂ a. NBS, (PhCO₂), b. Bra, FeBr, c. Br₂, H d. OH e. NaOH(s), A 1. HNO₂, H₂SO 9. H₂ CrO Answer: NO₂ Reagents available. h. CH, CI, AICI, o. CuCN 1. CH₂ CH₂ Br p. H₂O, A 1. CH₂O, A q. CH₂ CH₂ COCI, AICI, k. CH, COCI, AICI r. H₂NNH,, OH A 1. Mg, Et₂0 s. H₂. Pd/C m. CO₂ (s) then H₂0 t. H₂PO, n. HONO 0°C u. Cl₂, FeCla (Enter the letter(s) of the reagent(s) needed in the box, in the order that they must be used. No more than two steps are required to perform the synthesis. Note that a retrosynthetic arrow is used, and therefore the reactant is shown on the right.) Previous Nextarrow_forwardReagents Available a. H₂O, H₂SO4, HgSO4 b. BH3 then H₂O₂ c. NaNH2 d. CH3CH₂Br e. HCI, ether Select reagents from the above table to carry out each of the following reactions. If only a single step is required, select (none) from the drop down list. Reaction 1: Step 1: Step 2: Reaction 2: Step 1: Step 2: f. H₂, Lindlar catalyst g. Li, NH3 (liq) h. CH₂l2, Zn(Cu) i. H₂, Pd/C j. Br2, CH₂Cl2 ^ CH3CH₂CH₂C=CCH3 CH3CH₂CH₂C=CH ? ? Br Br \/ CH3CH₂CH₂CCCH3 Br Br CH3CH₂CH₂C=CCH₂CH3arrow_forwardA. OsO4 and NMO B. Br2 and H20 C. Hg(OAc)2, H2O and NaBH4, NaOH D. RCO3H E. BH3-THF and H2O2, NaOH Which reagent will complete this reaction?arrow_forward
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